Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card
8th Edition
ISBN: 9781305717497
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Textbook Question
Chapter 4, Problem 22QAP
Follow the directions of Question 21 for the following bases:
(a) toluidine, C7H9N
(b) strontium hydroxide
(c) indol, C8H6NH
(d) aqueous ammonia
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4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how
you confirmed the structure.
5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of
Limonene.
6. (1 pts) Predict the 1H NMR spectral data of R-Limonene.
Proton NMR: 5.3 pon multiplet (H Ring
Part VI.
Ca H 10 O is the molecular formula of compound Tom and gives the
in the table below. Give a possible structure for compound Tom.
13C
Signals summarized
C1
C2
C3
C4
C5
C6
C7
13C shift (ppm)
23.5
27.0
33.0
35.8
127
162
205
DEPT-90
+
DEPT-135
+
+
2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at
373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and
molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.
Chapter 4 Solutions
Bundle: Chemistry: Principles and Reactions, 8th, Loose-Leaf + OWLv2, 1 term (6 months) Printed Access Card
Ch. 4 - Write the formulas of the following compounds and...Ch. 4 - Prob. 2QAPCh. 4 - Describe how you would precipitate (a) zinc...Ch. 4 - Name the reagent, if any, that you would add to a...Ch. 4 - Write net ionic equations for the formation of (a)...Ch. 4 - Write net ionic equations to explain the formation...Ch. 4 - Decide whether a precipitate will form when the...Ch. 4 - Follow the directions of Question 7 for solutions...Ch. 4 - Write a net ionic equation for any precipitation...Ch. 4 - Follow the directions for Question 9 for the...
Ch. 4 - What volume of 0.2500 M cobalt(III) sulfate is...Ch. 4 - Prob. 12QAPCh. 4 - A 50.00-mL sample of 0.0250 M silver nitrate is...Ch. 4 - Aluminum ions react with carbonate ions to form an...Ch. 4 - When Na3PO4 and Ca(NO3)2 are combined, the...Ch. 4 - When solutions of aluminum sulfate and sodium...Ch. 4 - Prob. 17QAPCh. 4 - Prob. 18QAPCh. 4 - Prob. 19QAPCh. 4 - Follow the directions of Question 19 for the...Ch. 4 - For an acid-base reaction, what is the reacting...Ch. 4 - Follow the directions of Question 21 for the...Ch. 4 - Prob. 23QAPCh. 4 - Prob. 24QAPCh. 4 - Consider the following generic equation: H+(aq)+...Ch. 4 - Consider the following generic equation...Ch. 4 - Prob. 27QAPCh. 4 - Prob. 28QAPCh. 4 - Prob. 29QAPCh. 4 - Consider several 25.00-mL solutions of perchloric...Ch. 4 - Prob. 31QAPCh. 4 - A student tries to determine experimentally the...Ch. 4 - Prob. 33QAPCh. 4 - For a product to be called vinegar, it must...Ch. 4 - The percentage of sodium hydrogen carbonate,...Ch. 4 - Prob. 36QAPCh. 4 - An artificial fruit beverage contains 12.0 g of...Ch. 4 - Lactic acid, C3H6O3 is the acid present in sour...Ch. 4 - Prob. 39QAPCh. 4 - Prob. 40QAPCh. 4 - Assign oxidation numbers to each element in (a)...Ch. 4 - Assign oxidation numbers to each element in (a)...Ch. 4 - Classify each of the following half-reactions as...Ch. 4 - Classify each of the following half-reactions as...Ch. 4 - Classify each of the following half-reactions as...Ch. 4 - Prob. 46QAPCh. 4 - For each unbalanced equation given below • write...Ch. 4 - Prob. 48QAPCh. 4 - A solution of potassium permanganate reacts with...Ch. 4 - Prob. 50QAPCh. 4 - Hydrogen gas is bubbled into a solution of barium...Ch. 4 - Consider the reaction tween silver and nitric acid...Ch. 4 - The molarity of iodine in solution can be...Ch. 4 - A wire weighing 0.250 g and containing 92.50% Fe...Ch. 4 - Glycerol (C3H8O3) is commonly used as an additive...Ch. 4 - Laws passed in some states define a drunk driver...Ch. 4 - A sample of limestone weighing 1.005 g is...Ch. 4 - The iron content of hemoglobin is determined by...Ch. 4 - In order to determine the purity of ammonium...Ch. 4 - Gold metal will dissolve only in aqua regia, a...Ch. 4 - Prob. 61QAPCh. 4 - Ten mL of concentrated H3PO4 (91.7% by mass,...Ch. 4 - Consider the following balanced redox reaction in...Ch. 4 - Prob. 64QAPCh. 4 - Using circles to represent cations and squares to...Ch. 4 - Assuming that circles represent cations and...Ch. 4 - Consider four beakers. Beaker A has an aqueous...Ch. 4 - The following figures represent species before and...Ch. 4 - A student is asked to identify the metal nitrate...Ch. 4 - Three students titrate different samples of the...Ch. 4 - Calcium in blood or urine can be determined by...Ch. 4 - Copper metal can reduce silver ions to metallic...Ch. 4 - Copper metal can reduce silver ions to metallic...Ch. 4 - A solution contains both iron(II) and iron(III)...Ch. 4 - A student is given 0.930 g of an unknown acid,...Ch. 4 - Solid iron(III) hydroxide is added to 625 mL of...Ch. 4 - A 300.0-g sample of a solid is made up of a...Ch. 4 - When 85.0 mL of 0.250 M Ba(OH)2 solution is added...
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- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
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