The net-ionic equation for the given reaction should be determined. Concept Introduction: When two aqueous solutions are mixed together, this may or may not result in formation of an insoluble solid in the solution. This insoluble solid is called precipitate and this reaction is called precipitation reaction. For example, a reaction in which A and C displace each other from their respective solutions. Since two displacement takes place, this reaction is also called double displacement reaction. AB(aq)+CD(aq) → AD(s)+CB(aq) AD(s) represents a precipitate. Sometime a gaseous product is also formed, in that case we represent the equation with the phase mentioned as (g). AB(aq)+CD(aq) → AD(g) ↑ +CB(aq) .
The net-ionic equation for the given reaction should be determined. Concept Introduction: When two aqueous solutions are mixed together, this may or may not result in formation of an insoluble solid in the solution. This insoluble solid is called precipitate and this reaction is called precipitation reaction. For example, a reaction in which A and C displace each other from their respective solutions. Since two displacement takes place, this reaction is also called double displacement reaction. AB(aq)+CD(aq) → AD(s)+CB(aq) AD(s) represents a precipitate. Sometime a gaseous product is also formed, in that case we represent the equation with the phase mentioned as (g). AB(aq)+CD(aq) → AD(g) ↑ +CB(aq) .
Solution Summary: The author explains that the net-ionic equation for the given reaction should be determined.
The net-ionic equation for the given reaction should be determined.
Concept Introduction:
When two aqueous solutions are mixed together, this may or may not result in formation of an insoluble solid in the solution. This insoluble solid is called precipitate and this reaction is called precipitation reaction.
For example, a reaction in which A and C displace each other from their respective solutions. Since two displacement takes place, this reaction is also called double displacement reaction.
AB(aq)+CD(aq)→AD(s)+CB(aq)
AD(s) represents a precipitate.
Sometime a gaseous product is also formed, in that case we represent the equation with the phase mentioned as (g).
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 4 Solutions
Introduction To General, Organic, And Biochemistry
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