
Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Question
Chapter 4, Problem 56P
Interpretation Introduction
Interpretation: The energy required or needed can be calculated as follows:
Concept Introduction:
The heat required can be calculated as follows:
Here, m is mass of substance, c is specific heat capacity and
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 4 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 4.2 - Problem 4-1 Following is an unbalanced equation...Ch. 4.2 - Problem 4-2 Balance this equation:Ch. 4.2 - Prob. 4.3QCCh. 4.3 - Problem 4-4 When a solution of copper(II)...Ch. 4.4 - Problem 4-5 In each equation, identify the...Ch. 4.5 - Problem 4-6 What is (a) the molecular weight of...Ch. 4.6 - Prob. 4.7QCCh. 4.6 - Problem 4-8 We wish to weigh 2.84 mol of sodium...Ch. 4.6 - Problem 4-9 How many moles of C atoms, H atoms,...Ch. 4.6 - Problem 4-10 How many moles of copper(I) ions,...
Ch. 4.6 - Prob. 4.11QCCh. 4.7 - Prob. 4.12QCCh. 4.7 - Prob. 4.13QCCh. 4.7 - Problem 4-14 Ethanol is produced industrially by...Ch. 4.7 - Prob. 4.15QCCh. 4.7 - Prob. 4.16QCCh. 4.8 - How many calories are required to heat 731g of...Ch. 4.8 - A 100g piece of iron at 25C is heated by adding...Ch. 4.8 - It required 88.2 cal to heat 13.4g of an unknown...Ch. 4.9 - Solid iron and oxygen gas react to form solid...Ch. 4 - 4-17 Balance each equation.Ch. 4 - 4-18 Balance each equation.Ch. 4 - Prob. 3PCh. 4 - 4-20 Calcium oxide is prepared by heating...Ch. 4 - 4-21 The brilliant white light in some firework...Ch. 4 - Prob. 6PCh. 4 - 4-23 When solid carbon burns in a limited supply...Ch. 4 - Prob. 8PCh. 4 - 4-25 In the chemical test for arsenic, the gas...Ch. 4 - Prob. 10PCh. 4 - Prob. 11PCh. 4 - 4-28 Answer true or false. (a) A net ionic...Ch. 4 - 4-29 Balance these net ionic equations. (a)...Ch. 4 - 4-30 In the equation (a) Identify the spectator...Ch. 4 - 4-31 Predict whether a precipitate will form when...Ch. 4 - 4-32 When a solution of ammonium chloride is added...Ch. 4 - 4-33 When a solution of hydrochloric acid, HCl, is...Ch. 4 - Prob. 18PCh. 4 - Prob. 19PCh. 4 - 4-36 Using the solubility generalizations given in...Ch. 4 - 4-37 Answer true or false. (a) When a substance is...Ch. 4 - Prob. 22PCh. 4 - Prob. 23PCh. 4 - Prob. 24PCh. 4 - Prob. 25PCh. 4 - 4-42 Calculate the formula weight of: (a) KCl (b)...Ch. 4 - 4-43 Calculate the molecular weight of: (a)...Ch. 4 - 4-44 Answer true or false. (a) The mole is a...Ch. 4 - 4-45 Calculate the number of moles in: (a) 32 g of...Ch. 4 - 4-46 Calculate the number of grams in: (a) 1.77...Ch. 4 - 4-47 Calculate the number of moles of: (a) O atoms...Ch. 4 - 4-48 Calculate the number of moles of: (a) S2-...Ch. 4 - 4-49 Calculate the number of: (a) nitrogen atoms...Ch. 4 - 4-50 How many molecules are in each of the...Ch. 4 - 4-51 What is the mass in grams of each number of...Ch. 4 - 4-52 The molecular weight of hemoglobin is about...Ch. 4 - 4-53 A typical deposit of cholesterol, C27H46O, in...Ch. 4 - 4-54 Answer true or false. (a) Stoichiometry is...Ch. 4 - 4-55 For the reaction: (a) How many moles of N2...Ch. 4 - 4-56 Magnesium reacts with sulfuric acid according...Ch. 4 - 4-57 Chloroform, CHCl3, is prepared industrially...Ch. 4 - 4-58 At one time, acetaldehyde was prepared...Ch. 4 - 4-59 Chlorine dioxide, ClO2, is used for bleaching...Ch. 4 - 4-60 Ethanol, C2H6O, is added to gasoline to...Ch. 4 - 4-61 In photosynthesis, green plants convert CO2...Ch. 4 - 4-62 Iron ore is converted to iron by heating it...Ch. 4 - Prob. 47PCh. 4 - 4-64 Aspirin is made by the reaction of salicylic...Ch. 4 - 4-65 Suppose the preparation of aspirin from...Ch. 4 - 4-66 Benzene reacts with bromine to produce...Ch. 4 - 4-67 Ethyl chloride is prepared by the reaction of...Ch. 4 - 4-68 Diethyl ether is made from ethanol according...Ch. 4 - Prob. 53PCh. 4 - How many calories are required to heat the...Ch. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - 4-71 Which of these reactions are exothermic, and...Ch. 4 - Prob. 60PCh. 4 - Prob. 61PCh. 4 - Prob. 62PCh. 4 - Prob. 63PCh. 4 - Prob. 64PCh. 4 - 4-77 To convert 1 mol of iron(III) oxide to its...Ch. 4 - 4-78 (Chemical Connections 4A) How does fluoride...Ch. 4 - Prob. 67PCh. 4 - Prob. 68PCh. 4 - 4-81 (Chemical Connections 4C) Balance the lithium...Ch. 4 - 4-82 When gaseous dinitrogen pentoxide, N2O5, is...Ch. 4 - Prob. 71PCh. 4 - Prob. 72PCh. 4 - Prob. 73PCh. 4 - 4-86 When an aqueous solution of Na3PO4 is added...Ch. 4 - Prob. 75PCh. 4 - 4-88 Chlorophyll, the compound responsible for the...Ch. 4 - 4-89 If 7.0 kg of is added to 11.0 kg of to form...Ch. 4 - 4-90 Lead(lI) nitrate and aluminum chloride react...Ch. 4 - 4-91 Assume that the average red blood cell has a...Ch. 4 - 4-92 Reaction of pentane, C5H12, with oxygen, O2,...Ch. 4 - 4-93 Ammonia is prepared industrially by the...Ch. 4 - 4-94 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is...Ch. 4 - Prob. 83PCh. 4 - Prob. 84PCh. 4 - Prob. 85PCh. 4 - Prob. 86PCh. 4 - Prob. 87PCh. 4 - Prob. 88PCh. 4 - Prob. 89PCh. 4 - Prob. 90PCh. 4 - Prob. 91PCh. 4 - 4-102 Aspartame, an artificial sweetener used as a...Ch. 4 - 4-103 Caffeine, a central nervous system...Ch. 4 - Prob. 94P
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Similar questions
- For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forwardPredict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forward
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
- give example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward(Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward
- 3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forwardA 0.552-g sample of an unknown acid was dissolved in water to a total volume of 20.0 mL. This sample was titrated with 0.1103 M KOH. The equivalence point occurred at 29.42 mL base added. The pH of the solution at 10.0 mL base added was 3.72. Determine the molar mass of the acid. Determine the Ka of the acid.arrow_forward
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