EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 9781319188962
Author: VOLLHARDT
Publisher: VST
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Chapter 3.7, Problem 3.7E
Interpretation Introduction
Interpretation: Various products formed from the radical monochlorination of butane along with ratios of different products should be written.
Concept introduction: The monochlorination performed with ultraviolet light proceeds via radical chain mechanism. Chlorine transforms
The fundamental radical chain mechanism is summarized in the illustration as follows:
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
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120
80
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DEPT 135
T
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Draw the unknown amide.
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Chapter 3 Solutions
EBK ORGANIC CHEMISTRY
Ch. 3.1 - Prob. 3.2TIYCh. 3.1 - Prob. 3.3ECh. 3.4 - Prob. 3.5TIYCh. 3.5 - Prob. 3.6ECh. 3.7 - Prob. 3.7ECh. 3.7 - Prob. 3.9TIYCh. 3.9 - Prob. 3.11TIYCh. 3.11 - Prob. 3.12ECh. 3 - Prob. 15PCh. 3 - Prob. 16P
Ch. 3 - Prob. 17PCh. 3 - Prob. 18PCh. 3 - Prob. 19PCh. 3 - Prob. 20PCh. 3 - Prob. 21PCh. 3 - Prob. 22PCh. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Prob. 29PCh. 3 - Prob. 30PCh. 3 - Prob. 31PCh. 3 - Prob. 32PCh. 3 - Prob. 33PCh. 3 - Prob. 34PCh. 3 - Prob. 35PCh. 3 - Prob. 36PCh. 3 - Prob. 37PCh. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Prob. 41PCh. 3 - Prob. 42PCh. 3 - Prob. 43PCh. 3 - Prob. 44PCh. 3 - Prob. 45PCh. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48PCh. 3 - Prob. 49PCh. 3 - Prob. 50PCh. 3 - Prob. 51P
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