EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 9781319188962
Author: VOLLHARDT
Publisher: VST
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Chapter 3, Problem 36P
Interpretation Introduction

Interpretation: The mechanism of chlorination of methane with SO2Cl2 as initiator should be written.

Concept introduction: The monochlorination performed with ultraviolet light proceeds via radical chain mechanism. Chlorine transforms CH4 into chloromethane as the major halogenated product with variety of side products due to various possibilities of chain termination.

The fundamental radical chain mechanism is summarized in the illustration below:

  EBK ORGANIC CHEMISTRY, Chapter 3, Problem 36P

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