EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 9781319188962
Author: VOLLHARDT
Publisher: VST
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Chapter 3, Problem 27P
(a)
Interpretation Introduction
Interpretation: The isomeric products obtained after monobromination of propane should be drawn.
Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.
Tertiary
The phenomenon of hyperconjugation refers to donation of
(b)
Interpretation Introduction
Interpretation: The approximate ratio of products obtained, major product of monobromination and whether the selectivity exhibited by bromine is sufficient enough for formation of isomeric products in good yields should be drawn.
Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.
Tertiary
The phenomenon of hyperconjugation refers to donation of
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
200
160
120
80
40
0
200
160
120
80
40
0
DEPT 135
T
200
160
120
80
40
0
Draw the unknown amide.
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Dow
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Chapter 3 Solutions
EBK ORGANIC CHEMISTRY
Ch. 3.1 - Prob. 3.2TIYCh. 3.1 - Prob. 3.3ECh. 3.4 - Prob. 3.5TIYCh. 3.5 - Prob. 3.6ECh. 3.7 - Prob. 3.7ECh. 3.7 - Prob. 3.9TIYCh. 3.9 - Prob. 3.11TIYCh. 3.11 - Prob. 3.12ECh. 3 - Prob. 15PCh. 3 - Prob. 16P
Ch. 3 - Prob. 17PCh. 3 - Prob. 18PCh. 3 - Prob. 19PCh. 3 - Prob. 20PCh. 3 - Prob. 21PCh. 3 - Prob. 22PCh. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Prob. 29PCh. 3 - Prob. 30PCh. 3 - Prob. 31PCh. 3 - Prob. 32PCh. 3 - Prob. 33PCh. 3 - Prob. 34PCh. 3 - Prob. 35PCh. 3 - Prob. 36PCh. 3 - Prob. 37PCh. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Prob. 41PCh. 3 - Prob. 42PCh. 3 - Prob. 43PCh. 3 - Prob. 44PCh. 3 - Prob. 45PCh. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48PCh. 3 - Prob. 49PCh. 3 - Prob. 50PCh. 3 - Prob. 51P
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