EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 9781319188962
Author: VOLLHARDT
Publisher: VST
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Chapter 3, Problem 43P

(a)

Interpretation Introduction

Interpretation: The heat of combustion per gram needs to be determined for the mentioned hydrocarbons.

Concept Introduction: The heat of combustion is calculated generally in unit kcal/mol. To convert it into kcal/g, the value needs to be divided with the mass of substance in its 1 mol.

(b)

Interpretation Introduction

Interpretation: The same calculations as in part (a) needs to be done for ethanol.

Concept Introduction: The heat of combustion is calculated generally in unit kcal/mol. To convert it into kcal/g, the value needs to be divided with the mass of substance in its 1 mol.

(c)

Interpretation Introduction

Interpretation: Whether the fuel capability of hydrocarbon is more or less than ethanol needs to be determined.

Concept Introduction: The heat of combustion is calculated generally in unit kcal/mol. To convert it into kcal/g, the value needs to be divided with the mass of substance in its 1 mol.

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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 40 0 DEPT 135 T 200 160 120 80 40 0 Draw the unknown amide. Select Dow Templates More Frage
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