Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 3.7, Problem 27P
List the compounds in each set from highest boiling to lowest boiling:
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Naming and drawing secondary
Write the systematic (IUPAC) name for each of the following organic molecules:
CH3
Z
structure
CH3
CH2
CH2
N-CH3
CH3-CH2-CH2-CH-CH3
NH
CH3-CH-CH2-CH2-CH2-CH2-CH2-CH3
Explanation
Check
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name
☐
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G
C
This question shows how molecular orbital (MO) theory can be used to understand the chemical
properties of elemental oxygen O₂ and its anionic derivative superoxide Oz.
a)
Draw the MO energy diagram for both O2 and O2. Clearly label your diagram with atomic orbital names
and molecular orbital symmetry labels and include electrons.
Draw the Lewis structure of O2. How does the MO description of O2 differ from the Lewis structure, and
how does this difference relate to the high reactivity and magnetic properties of oxygen?
) Use the MO diagram in (a) to explain the difference in bond length and bond energy between superoxide
ion (Oz, 135 pm, 360 kJ/mol) and oxygen (O2, 120.8 pm, 494 kJ/mol).
Please draw
Chapter 3 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Draw the structure for each of the following...Ch. 3.1 - Name the following compounds:Ch. 3.1 - Prob. 7PCh. 3.2 - What is each compounds systematic name?Ch. 3.2 - Prob. 11PCh. 3.3 - Prob. 12PCh. 3.3 - Convert the following condensed structures into...Ch. 3.3 - The molecular formula for ethyl alcohol (CH3CH2OH)...
Ch. 3.3 - Draw a condensed and a skeletal structure for the...Ch. 3.3 - What is each compounds systematic name?Ch. 3.4 - Prob. 17PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.5 - Are the following compounds primary, secondary, or...Ch. 3.5 - Name the following amines and tell whether they...Ch. 3.5 - Draw the structures and provide systematic names...Ch. 3.6 - Predict the approximate size of the following bond...Ch. 3.7 - What is the smallest straight-chain alkane that is...Ch. 3.7 - Prob. 24PCh. 3.7 - Prob. 25PCh. 3.7 - Prob. 26PCh. 3.7 - List the compounds in each set from highest...Ch. 3.8 - Rank the following compounds in each set from most...Ch. 3.8 - In which solvent would cyclohexane have the lowest...Ch. 3.8 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - a. Draw the three staggered conformations and the...Ch. 3.9 - a. Draw the most stable conformation of pentane...Ch. 3.11 - Draw 1,2,3,4,5,6-hexachlorocyclohexane with a. all...Ch. 3.12 - At any one time, would you expect there to be more...Ch. 3.13 - Prob. 36PCh. 3 - a. How many hydrogens does an alkane with 17...Ch. 3 - Prob. 2PCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Name the following amines and tell whether they...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - What is each compounds name? a. CH3CH2CH2OCH2CH3Ch. 3 - Draw the structural formula for an alkane that has...Ch. 3 - Which has a. the higher boiling point:...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 51PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - Prob. 53PCh. 3 - For rotation about the C-3 8 C-4 bond of...Ch. 3 - Prob. 55PCh. 3 - What is each compounds systematic name?Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Draw the nine constitutional isomers with...Ch. 3 - Prob. 59PCh. 3 - Prob. 60PCh. 3 - Prob. 61PCh. 3 - Using Newman projections, draw the most stable...Ch. 3 - For each of the following disubstituted...Ch. 3 - Prob. 64PCh. 3 - Prob. 65PCh. 3 - What is each compounds systematic name?Ch. 3 - Prob. 67PCh. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Prob. 69PCh. 3 - Prob. 70PCh. 3 - a. Draw a potential energy diagram for rotation...
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- -Page: 8 nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]". What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry of [Co(H2O)]? b) Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron configurations of [Co(H2O)]: Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of [Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1 kJ/mol) Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low in configuration vs in the high spin configuration? What can you say about the importance of exchange energy 07arrow_forwardDraw everything please on a piece of paper explaining each steparrow_forwardDefine crystalline, polycrystalline and amorphous materials What crystal system and Bravais lattices are shown in the figure immediately below? What do a, b, C, a, ẞ and y represent and what are their values? You can label the Bravais lattices directly above or under the figure. C aarrow_forward
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