The given compound has to be identified as cis or trans isomer. Concept introduction: Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers. Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in ( cis ) and ( trans ) configurations know as geometric isomerism. Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to ( 109 .5 0 ) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

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Answer 1

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

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Answer 2

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

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Answer 3

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

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Answer 4

Question

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

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Answer 5

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 6

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 7

Chapter 3, Problem 60P

(a)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given compound has to be identified as cis or trans isomer.

Concept introduction:

Conformers: The different spatial arrangements of the atoms the result from rotation about a single bond is called conformational isomers.

Stereoisomerism (or) geometric isomerism: It is known as cis-trans isomerism or E-Z isomerism is a form of stereoisomerism the each of two or more chemical compounds having the same molecular formula but a different geometric arrangement; an unsaturated compound or ring compound in which rotation around a carbon bond is restricted, as in (cis) and (trans) configurations know as geometric isomerism.

Relative stability of cyclohexane: The most stable conformation of cyclohexane is the chair shown to the right, the respective carbon (-C-C-) bonds are it close to (109.50) it is almost free of angle strain, it is also a fully staggered conformation and so is free of torsional strain. So the chair conformation is the most stable conformation.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Draw the structure for each of the following...Ch. 3.1 - Name the following compounds:Ch. 3.1 - Prob. 7P Ch. 3.2 - What is each compounds systematic name?Ch. 3.2 - Prob. 11P Ch. 3.3 - Prob. 12P Ch. 3.3 - Convert the following condensed structures into...Ch. 3.3 - The molecular formula for ethyl alcohol (CH3CH2OH)...

Solution Summary: The author explains that the given compound has to be identified as cis or trans isomer.

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Chapter 3 Solutions