Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer. Concept introduction: The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction. Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer. Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions .

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Answer 1

Question

Chapter 3, Problem 64P

Interpretation Introduction

Interpretation:

Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer.

Concept introduction:

The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction.

Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer.

Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions.

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Answer 2

Question

Chapter 3, Problem 64P

Interpretation Introduction

Interpretation:

Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer.

Concept introduction:

The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction.

Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer.

Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions.

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Answer 3

Question

Chapter 3, Problem 64P

Interpretation Introduction

Interpretation:

Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer.

Concept introduction:

The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction.

Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer.

Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions.

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Answer 4

Question

Chapter 3, Problem 64P

Interpretation Introduction

Interpretation:

Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer.

Concept introduction:

The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction.

Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer.

Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions.

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Answer 5

Chapter 3, Problem 64P

Interpretation Introduction

Interpretation:

Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer.

Concept introduction:

The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction.

Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer.

Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions.

Answer 6

Chapter 3, Problem 64P

Interpretation Introduction

Interpretation:

Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer.

Concept introduction:

The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction.

Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer.

Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions.

Answer 7

Chapter 3, Problem 64P

Interpretation Introduction

Interpretation:

Check whether the trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer compared with the diaxial-substituted conformer.

Concept introduction:

The axial substituent interferes with the axial hydrogens on C3 and C5 carbons. This interference generally called as 1, 3-diaxial interaction.

Considering, 1,4-disubstitutedcyclohexane the same substituents on the axial or equatorial position gives the trans isomer while the same substituent on the axial and equatorial position gives the cis isomer.

Among this the equatorial isomer is more stable due to the absence of 1,3-diaxial interactions.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 3.1 - Name each of the following:Ch. 3.1 - Draw the structures and name the four...Ch. 3.1 - Draw the structure for each of the following...Ch. 3.1 - Name the following compounds:Ch. 3.1 - Prob. 7P Ch. 3.2 - What is each compounds systematic name?Ch. 3.2 - Prob. 11P Ch. 3.3 - Prob. 12P Ch. 3.3 - Convert the following condensed structures into...Ch. 3.3 - The molecular formula for ethyl alcohol (CH3CH2OH)...

Solution Summary: The author analyzes whether trans-1,4-dimethylcyclohexane or cis-1-tertbutyl-3-methylcyclexans have a higher percentage of the diequatorial-sub

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