Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 3.10, Problem 8P
The following questions relate to a cyclohexane ring in the chair conformation shown.
Is a methyl group at
Is a methyl group that is “up” at
Place a methyl group at
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Suppose sodium sulfate has been gradually added to 100 mL of a solution containing calcium ions and strontium ions, both at 0.15 mol/L. Indicate the alternative that presents the percentage of strontium ions that will have precipitated when the calcium sulfate begins to precipitate.
Data: Kps of calcium sulfate: 2.4x10 ⁻ ⁵; Kps of strontium sulfate: 3.2x10 ⁻ ⁷
A) 20,2 %
B) 36,6 %
C) 62,9 %
D) 87,5 %
E) 98.7%
14:43 A
Candidate Identification
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14. The following diagrams represent
hypothetical membrane structures with
their components numbered from 1 to 6.
Based on the figures and your knowledge
of biological membranes, select the
correct alternative.
|
3
5
||
人
2
500000
6
A) Structures 1, 3, 5, 2 and 4 are present
in a constantly fluid arrangement that
allows the selectivity of the movement
○ of molecules. Structure 4, present
integrally or peripherally, is responsible
for this selection, while the quantity of 6
regulates the fluidity.
B) The membranes isolate the cell from
the environment, but allow the passage
of water-soluble molecules thanks to
the presence of 2 and 3. The membrane
in scheme is more fluid than that in
55
12. Mark the correct statement about
reactions a and b :
a.
Br
+ -OH
Br
b.
+ Br
H₂O
+
Br
-OH
+
H₂O
A) The reactions are elimination
reactions, with reaction "a" being of type
E2 and reaction "b" being of type E1.
B) Reaction "a" is an E2 type elimination
occurring in one step and reaction "b" is
an SN1 type substitution.
C) Both reactions can result in the
formation of carbocation, but in reaction
"b" the most stable carbocation will be
formed.
D) Both reactions occur at the same rate
○ and have the same number of reaction
steps.
E) Reaction "b" is an E2 type elimination
occurring in two steps and reaction "a" is
an SN2 type substitution.
Chapter 3 Solutions
Organic Chemistry - Standalone book
Ch. 3.1 - Identify the alkanes corresponding to each of the...Ch. 3.1 - Find the conformations in Figure 3.4 in which the...Ch. 3.2 - Sketch a potential energy diagram for rotation...Ch. 3.2 - Acetylcholine is a neurotransmitter in the central...Ch. 3.2 - Prob. 5PCh. 3.5 - The heats of combustion of ethylcyclopropane and...Ch. 3.8 - Prob. 7PCh. 3.10 - The following questions relate to a cyclohexane...Ch. 3.10 - Draw the most stable conformation of...Ch. 3.11 - Prob. 10P
Ch. 3.11 - Prob. 11PCh. 3.12 - Based on what you know about disubstituted...Ch. 3.12 - Write structural formulas for the most stable...Ch. 3.14 - Cubane (C4H8) is the common name of the polycyclic...Ch. 3.14 - Prob. 15PCh. 3.14 - Prob. 16PCh. 3.14 - Prob. 17PCh. 3.14 - Prob. 18PCh. 3.15 - Prob. 19PCh. 3 - Give the IUPAC names of each of the following: (a)...Ch. 3 - Draw Newman projections for the gauche and...Ch. 3 - Identify all atoms that are (a) anti and (b)...Ch. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Oxidation of 4-tert-butylthiane proceeds according...Ch. 3 - The following are representations of two forms of...Ch. 3 - Draw (a) a Newman projection of the most stable...Ch. 3 - Write a structural formula for the most stable...Ch. 3 - Sight down the C-2-C-3 bond, and draw Newman...Ch. 3 - Prob. 34PCh. 3 - Sketch an approximate potential energy diagram for...Ch. 3 - Prob. 36PCh. 3 - Even though the methyl group occupies an...Ch. 3 - Which do you expect to be the more stable...Ch. 3 - Arrange the trimethylcyclohexane isomers shown in...Ch. 3 - Identify the more stable stereoisomer in each of...Ch. 3 - One stereoisomer of 1,1,3,5-tetramethylcyclohexane...Ch. 3 - One of the following two stereoisomers is...Ch. 3 - In each of the following groups of compounds,...Ch. 3 - The heats of combustion of the more and less...Ch. 3 - The measured dipole moment of ClCH2CH2Cl is 1.12D....Ch. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48DSPCh. 3 - Prob. 49DSPCh. 3 - Prob. 50DSPCh. 3 - Prob. 51DSPCh. 3 - Prob. 52DSPCh. 3 - Prob. 53DSP
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