
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 3, Problem 53DSP
Interpretation Introduction
Interpretation:
The dihedral angles in the
Concept introduction:
In the chair form of cyclohexane, when two substituents on adjacent carbon atoms are both axial, the dihedral angle between them is
When a substituent on one carbon atom is axial and the substituent on adjacent carbon atoms is equatorial, the dihedral angle between them is
When two substituents on adjacent carbon atoms are both equatorial, the dihedral angle between them is
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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not
themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting
four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation
you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be
both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the
four structures.
Compound C
Possible conformations (circle one):
Дет
Lab Data
The distance entered is out of the expected range.
Check your calculations and conversion factors.
Verify your distance. Will the gas cloud be closer to the cotton ball with HCI or NH3?
Did you report your data to the correct number of significant figures?
- X
Experimental Set-up
HCI-NH3
NH3-HCI
Longer Tube
Time elapsed (min)
5 (exact)
5 (exact)
Distance between cotton balls (cm)
24.30
24.40
Distance to cloud (cm)
9.70
14.16
Distance traveled by HCI (cm)
9.70
9.80
Distance traveled by NH3 (cm)
14.60
14.50
Diffusion rate of HCI (cm/hr)
116
118
Diffusion rate of NH3 (cm/hr)
175.2
175.2
How to measure distance and calculate rate
For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically:
1:1 (one mole of EDTA per mole of metal ion)
2:1 (two moles of EDTA per mole of metal ion)
1:2 (one mole of EDTA per two moles of metal ion)
None of the above
Chapter 3 Solutions
Organic Chemistry - Standalone book
Ch. 3.1 - Identify the alkanes corresponding to each of the...Ch. 3.1 - Find the conformations in Figure 3.4 in which the...Ch. 3.2 - Sketch a potential energy diagram for rotation...Ch. 3.2 - Acetylcholine is a neurotransmitter in the central...Ch. 3.2 - Prob. 5PCh. 3.5 - The heats of combustion of ethylcyclopropane and...Ch. 3.8 - Prob. 7PCh. 3.10 - The following questions relate to a cyclohexane...Ch. 3.10 - Draw the most stable conformation of...Ch. 3.11 - Prob. 10P
Ch. 3.11 - Prob. 11PCh. 3.12 - Based on what you know about disubstituted...Ch. 3.12 - Write structural formulas for the most stable...Ch. 3.14 - Cubane (C4H8) is the common name of the polycyclic...Ch. 3.14 - Prob. 15PCh. 3.14 - Prob. 16PCh. 3.14 - Prob. 17PCh. 3.14 - Prob. 18PCh. 3.15 - Prob. 19PCh. 3 - Give the IUPAC names of each of the following: (a)...Ch. 3 - Draw Newman projections for the gauche and...Ch. 3 - Identify all atoms that are (a) anti and (b)...Ch. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Oxidation of 4-tert-butylthiane proceeds according...Ch. 3 - The following are representations of two forms of...Ch. 3 - Draw (a) a Newman projection of the most stable...Ch. 3 - Write a structural formula for the most stable...Ch. 3 - Sight down the C-2-C-3 bond, and draw Newman...Ch. 3 - Prob. 34PCh. 3 - Sketch an approximate potential energy diagram for...Ch. 3 - Prob. 36PCh. 3 - Even though the methyl group occupies an...Ch. 3 - Which do you expect to be the more stable...Ch. 3 - Arrange the trimethylcyclohexane isomers shown in...Ch. 3 - Identify the more stable stereoisomer in each of...Ch. 3 - One stereoisomer of 1,1,3,5-tetramethylcyclohexane...Ch. 3 - One of the following two stereoisomers is...Ch. 3 - In each of the following groups of compounds,...Ch. 3 - The heats of combustion of the more and less...Ch. 3 - The measured dipole moment of ClCH2CH2Cl is 1.12D....Ch. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48DSPCh. 3 - Prob. 49DSPCh. 3 - Prob. 50DSPCh. 3 - Prob. 51DSPCh. 3 - Prob. 52DSPCh. 3 - Prob. 53DSP
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