Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
5th Edition
ISBN: 9781260170405
Author: SMITH
Publisher: MCG
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Chapter 31, Problem 31.37P
Interpretation Introduction
(a)
Interpretation: The three dimensional structure for the given steroid is to be drawn.
Concept introduction: In ball-and-stick model, each colored ball represents a specific atom and each stick represents a bond.
Interpretation Introduction
(b)
Interpretation: The structure of stereoisomer formed by the reduction of
Concept introduction: Ring-flipping converts equatorial bonds into axial bonds and axial bonds into equatorial bonds. The reduction of ketone into alcohol can be done by using reagent
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(d) Draw the structure of the expected product when monosaccharide B undergo
mutarotation upon dissolving in water in the presence of Tollens reagent (AGNO3,
NHẠOH).
он
OH
O.
OH
OH
OH
monosaccharide B
1. Consider the following molecules. Clearly circle the glycosidic bond on each structure. In the Spae
provided clearly describe the type of glycosidic bond illustrated.
HO-CH2
O.
H.
H.
OH
HO.
HO-CH2
OH
H.
H.
H.
OH
H.
OH
Но
H.
H.
H.
OH
OH
HOH2Ç
HO
OH
OH
CH2OH
HI
エー
エエー
1. Draw the structure of 1-linolenyl-2-arachidyl-3-phosphatidylserine
2. Draw the structure of testosterone, the primary male sex hormone, which has a ketogroup at carbon 3 instead of hydroxyl group, the double bond at carbon 4 instead atcarbon 5, and a hydroxyl group instead of the alkyl group at carbon 17
Chapter 31 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
Ch. 31 - Problem 31.1
One component of jojoba oil is a wax...Ch. 31 - Problem 31.2
How would you expect the melting...Ch. 31 - Problem 31.3
Draw the products formed when...Ch. 31 - Problem 31.4
The main fatty acid component of the...Ch. 31 - Prob. 31.5PCh. 31 - Problem 31.6
Draw the structure of a lecithin...Ch. 31 - Prob. 31.7PCh. 31 - Problem 31.8
Why are phospholipids, but not...Ch. 31 - Problem 31.9
Explain why regularly ingesting a...Ch. 31 - Problem 31.10
Locate the isoprene units in each...
Ch. 31 - Problem 31.11
Locate the isoprene units in...Ch. 31 - Problem 31.12
Write a stepwise mechanism for the...Ch. 31 - Prob. 31.13PCh. 31 - Prob. 31.14PCh. 31 - Prob. 31.15PCh. 31 - Prob. 31.16PCh. 31 - 31.17 Locate the isoprene units in each...Ch. 31 - Prob. 31.18PCh. 31 - Prob. 31.19PCh. 31 - Prob. 31.20PCh. 31 - Prob. 31.21PCh. 31 - 31.22 What is the structure of an optically...Ch. 31 - Prob. 31.23PCh. 31 - 31.24 Draw the structure of the following...Ch. 31 - Prob. 31.25PCh. 31 - Locate the isoprene units in each compound. a. e....Ch. 31 - 31.27 Classify each terpene and terpenoid in...Ch. 31 - 31.38 Draw the products formed when cholesterol is...Ch. 31 - 31.29 An isoprene unit can be thought of as having...Ch. 31 - 31.30 Draw a stepwise mechanism for the conversion...Ch. 31 - Prob. 31.31PCh. 31 - Prob. 31.32PCh. 31 - Draw three-dimensional structures f or each...Ch. 31 - Prob. 31.34PCh. 31 - Prob. 31.35PCh. 31 - Prob. 31.36PCh. 31 - Prob. 31.37PCh. 31 - 31.38 Draw the products formed when cholesterol is...Ch. 31 - 31.39 Draw a stepwise mechanism for the following...Ch. 31 - 31.40 Draw a stepwise mechanism for the following...Ch. 31 - Prob. 31.41P
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- D The following disaccharide contains a(n) (blank]-glycosidic linkage. HO CH₂OH ОН Oa-1,4 OB-1,4 a-1,6 O B-1,6 0 OH Question 6 double bond ssignments/syllabus ester bond ether bond amide bond HO A glycosidic bond between two monosaccharides can also be classified as a(n) [blank). OH OH Melebi OH MacBook Proarrow_forwarda. In an aqueous solution, d-glucose exists in equilibrium with two six-membered ring compounds. Draw the structures of these compounds.b. Which of the six-membered ring compounds will be the major product?arrow_forwardDraw the structure of CH3CH(OH)CH2CH2CHO, where -CHO represents an aldehyde group and answer the following questions: 1. What is the name of this compound? 2. Does this compound contain a chiral carbon? If so, what number carbon is chiral? 3. Does this compound give a positive Tollen's test? If so, what would be the observations for this test? Draw the structure for the product of adding Tollen's reagent to the aldehyde? No molecular formulas. 4. What is oxidized? What is reduced? 5. This compound can form a cyclic hemiacetal, since it has an internal OH group and an aldehyde group. What size ring would be formed from this cyclic hemiacetal?arrow_forward
- Draw the compound shown in the hemiacetal form as a pyranose in the more stable chair form. ww HO- HO. HO- HO- HO-arrow_forwardPart A What are glycosides, and how can they be formed? A glycoside is the acetal product that results from rerction of the hemiacetal -OH group of a carbohydrate with an aldehyd O A glycoside is the acetal product that results from reaction of the hemiacetal-OH group of a carbohydrate with an alcohol. A glycoside is the hemiacetal product that results from reaction of the acetal-OH group of a carbohydrate with an alcohol. Submit Previous Answers Request Answerarrow_forward4. What is one chemical test that can distinguish between 2-hexanone and glucose? Indicate the compound that will have a positive result to the test, if there is. 5. What is one chemical test that can distinguish between 1-hexanol and 3-methyl-3-pentanol? Indicate the compound that will have a positive result to the test, if there is. 6. What is one chemical test that can distinguish between 1-naphthol and 1-hexanol? Indicate the compound that will have a positive result to the test, if there is.arrow_forward
- The structure has what type of glycosidic linkage? a. b (1®4) b. b (1®6) c. a (1®4) d. a (1®6)arrow_forward1. What is the main sweetener in your gum? sucrose C₁2H22011 isomalt C12H24O11 mannitol C₁H₁406 maltitol C12H24O11 O sorbitol C6H₁406 Ⓒxyitol C-H12O5arrow_forward2. Draw the structural formulas for the reactants and products for the following reactions. Name the organic product that forms D and Earrow_forward
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