Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 31, Problem 31.21P
Interpretation Introduction
Interpretation: The possible constitutional isomers of as triacylglycerol formed from one mole of each palmitic acid, oleic and linoleic acid are to be drawn and the stereogenic centers are to be located in each constitutional isomer.
Concept introduction: Triacylglycerols are a type of lipids. They are composed of three fatty acids and glycerol. Simple triacylglycerol contains three same fatty acids while mixed triacylglycerol contains two or more different fatty acids. They are also known as triglycerides.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Stearidonic acid (C18H28O2) is an unsaturated fatty acid obtained fromoils isolated from hemp and blackcurrant
a.) What fatty acid is formed when stearidonic acid is hydrogenated withexcess H2 and a Pd catalyst?b.) What fatty acids are formed when stearidonic acid is hydrogenatedwith one equivalent of H2 and a Pd catalyst?c.) Draw the structure of a possible product formed when stearidonic acidis hydrogenated with one equivalent of H2 and a Pd catalyst, and onedouble bond is isomerized to a trans isomer.d.) How do the melting points of the following fatty acids compare:stearidonic acid; one of the products formed in part (b); the productdrawn in part (c)?
Which of the following molecules is least likely to be a fatty acid?
O
H₂C-(CH₂)-COOH
O
H₂C-CH(CH=CH-CH₂)-(CH₂-COOH
H₂C-(CH₂)-CH=CH-(CH₂)-COOH
(CH₂)-CH-(CH₂)-COOH
1. Some marine plankton contain triacylglycerols formed from the polyunsaturated fatty acid (PUFA) such as: CH3CH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2COOH
a) Draw the skeletal structure of the given PUFA showing the preffered stereogenic arrangement for a naturally-occuring lipid at each double bond.
b) Write the systematic name of the fatty acid.
c) What type of omega-n acid is this fatty acid?
d) Would you expect this fatty acid to be a soild or liquid at room temperature?
Chapter 31 Solutions
Organic Chemistry
Ch. 31 - Problem 31.1
One component of jojoba oil is a wax...Ch. 31 - Problem 31.2
How would you expect the melting...Ch. 31 - Problem 31.3
Draw the products formed when...Ch. 31 - Problem 31.4
The main fatty acid component of the...Ch. 31 - Prob. 31.5PCh. 31 - Problem 31.6
Draw the structure of a lecithin...Ch. 31 - Prob. 31.7PCh. 31 - Problem 31.8
Why are phospholipids, but not...Ch. 31 - Problem 31.9
Explain why regularly ingesting a...Ch. 31 - Problem 31.10
Locate the isoprene units in each...
Ch. 31 - Problem 31.11
Locate the isoprene units in...Ch. 31 - Problem 31.12
Write a stepwise mechanism for the...Ch. 31 - Prob. 31.13PCh. 31 - Prob. 31.14PCh. 31 - Prob. 31.15PCh. 31 - Prob. 31.16PCh. 31 - 31.17 Locate the isoprene units in each...Ch. 31 - Prob. 31.18PCh. 31 - Prob. 31.19PCh. 31 - Prob. 31.20PCh. 31 - Prob. 31.21PCh. 31 - 31.22 What is the structure of an optically...Ch. 31 - Prob. 31.23PCh. 31 - 31.24 Draw the structure of the following...Ch. 31 - Prob. 31.25PCh. 31 - Locate the isoprene units in each compound. a. e....Ch. 31 - 31.27 Classify each terpene and terpenoid in...Ch. 31 - 31.38 Draw the products formed when cholesterol is...Ch. 31 - 31.29 An isoprene unit can be thought of as having...Ch. 31 - 31.30 Draw a stepwise mechanism for the conversion...Ch. 31 - Prob. 31.31PCh. 31 - Prob. 31.32PCh. 31 - Draw three-dimensional structures f or each...Ch. 31 - Prob. 31.34PCh. 31 - Prob. 31.35PCh. 31 - Prob. 31.36PCh. 31 - Prob. 31.37PCh. 31 - 31.38 Draw the products formed when cholesterol is...Ch. 31 - 31.39 Draw a stepwise mechanism for the following...Ch. 31 - 31.40 Draw a stepwise mechanism for the following...Ch. 31 - Prob. 31.41P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Why is it safe for us to consume foods like vinegar that contain acetic acids?arrow_forwardDraw a structure for a lactone with 5 carbonsarrow_forwardWhich of the following is an omega 6 fatty acid? Fatty acid A: CH3(CH2)5CH=CH(CH2)7COOH Fatty acid B: CH3(CH2)8COOH Fatty acid C: CH3(CH2)7CH=CH(CH2)7COOH Fatty acid D: CH3(CH2)4CH=CH(CH2)7COOHarrow_forward
- Draw the organic products formed when cyclopentene is treated withfollowing reagent. mCPBAarrow_forwardDraw the organic products formed when attached compound is treated with H2, Pd-C. Indicate the three-dimensional structure of all stereoisomersformed.arrow_forwardDraw the products of the diethyl 2-ethylhexanedioate: (1) sodium ethoxide; (2) HClarrow_forward
- The following chemical reaction is used to synthesize a flavouring agent that has an aroma similar to bananas. H₂SO4(aq) CH3COOH(1) + CH₂(CH₂)₂OH(1) I || Identify the type of reaction that is represented by this synthesis. Select one: O hydrogenation O esterification O addition O substitution O elimination Identify the functional group and the IUPAC name for each of the three compounds in the reaction below: H₂SO4(aq) I Compound Functional Group IUPAC Name II CH₂COOH(1) + CH₂(CH₂)₂OH(1) I || III CH3COO(CH₂)₂CH₂(1) + H₂O(1) III IV ◆ → ◆ CH3COO(CH₂)₂CH₂(1) + H₂O(1) IV ||| ◆ ◆arrow_forwardDraw the structure of the triacylgyverol with three molecules of linoleic acid CH3(CH2)4-CH=CH-CH2-CH=CH-(CH2)7 - COOH (Linoleic acid)arrow_forwardIdentify the chiral centers in α-phellandrene, β-phellandrene, and limonene.arrow_forward
- Certain omega-3 fatty acids can be found only in animal sources, such as fatty fish. Two of these are eicosapentaenoic acid (EPA) [20:5] and docosahexaenoic acid (DHA) [22:6], both of which are ω-3 fatty acids. DHA has been shown to be important in healthy brain development, so it has recently been added to infant formulas. Breast milk is rich in DHA as long as the mother maintains a healthy diet that includes fish. Draw skeletal structures of the fatty acids EPA and DHA.arrow_forwardTrimyristin is obtained from coconut oil and has the molecular formula C45H86O6. On being heated with aqueous sodium hydroxide followed by acidification, trimyristin was converted to glycerol and tetradecanoic acid as the only products. What is the structure of trimyristin?arrow_forwardVanilla flavoring is either extracted from a tropical orchid or synthetically produced from wood pulp by-products. What differences in chemical structure would you expect in these two commercial products: vanilla extract and imitation vanilla extract?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning