Custom eBook for Organic Chemistry
Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Chapter 3, Problem 9E
Interpretation Introduction

Interpretation: The number of sigma and pi bonds in each molecule in the below structures should be reported.

  Custom eBook for Organic Chemistry, Chapter 3, Problem 9E , additional homework tip  1

Concept introduction: Bonds formed due to head-to-head overlap are termed sigma bond while ones formed by sideways or lateral overlap are named pi-bonds.

The 2 types of overlapping are as follows:

1. Head-on overlapping (sigma bond)

  Custom eBook for Organic Chemistry, Chapter 3, Problem 9E , additional homework tip  2

2. Sideway overlapping (pi bond)

  Custom eBook for Organic Chemistry, Chapter 3, Problem 9E , additional homework tip  3

A single bond has one σ bond, double bond has one σ bond along with one π bond while triple bond has two π bonds in addition to one σ bond.

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