The molecular ion S 3 N 3 − has the cyclic structure All S − N bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is − 0. 375 and on each S atom is + 0.0 41 . Show that this result is consistent with the overall + 1 charge on the molecular ion.
The molecular ion S 3 N 3 − has the cyclic structure All S − N bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is − 0. 375 and on each S atom is + 0.0 41 . Show that this result is consistent with the overall + 1 charge on the molecular ion.
The molecular ion
S
3
N
3
−
has the cyclic structure
All
S
−
N
bonds are equivalent.
(a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion.
(b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams.
(c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b).
(d) An advanced calculation suggests that the actual charge resident on each N atom is
−
0.
375
and on each S atom is
+
0.0
41
. Show that this result is consistent with the overall
+
1
charge on the molecular ion.
Don't used hand raiting and don't used Ai solution
Can you explain these two problems for me
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Blackboard
x Organic Chemistry II Lecture (m x
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Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
Problem 28 of 35
:OH H
HH
KO
Select to Edit Arrows
CH CH₂OK, CH CH2OH
5+
H
:0:
Done
Chapter 3 Solutions
Student Solutions Manual for Oxtoby/Gillis/Butler's Principles of Modern Chemistry, 8th
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