Biochemistry: Concepts and Connections
Biochemistry: Concepts and Connections
1st Edition
ISBN: 9780321839923
Author: Dean R. Appling, Spencer J. Anthony-Cahill, Christopher K. Mathews
Publisher: PEARSON
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Chapter 3, Problem 3P

The decomposition of crystalline N2O5 N 2 O 5 (s) 2NO 2 (g) + 1 2 O 2 (g) is an example of a reaction that is thermodynamically favored, even though it absorbs heat. At 25o C we have the following values for the standard state enthalpy and free energy changes of the reaction:

Δ H = + 109kJ/m01
Δ Go = -30.5kJ/m01

a. Calculate Δ So at 25o C.

b. Why is the entropy change so favorable for this reaction?

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