Biochemistry: Concepts and Connections
Biochemistry: Concepts and Connections
1st Edition
ISBN: 9780321839923
Author: Dean R. Appling, Spencer J. Anthony-Cahill, Christopher K. Mathews
Publisher: PEARSON
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Chapter 3, Problem 10P

Suppose a reaction has Δ Ho and Δ So values independent of temperature (i.e., assume these values are constant over some range of temperature). Show from this, and the equations given in this chapter, that ln K = -ΔH o RT + ΔS o R where K is the equilibrium constant. How could you use values of K determined at different temperatures to determine ΔH o for the reaction? (Hint. Recall that you are treating ΔH o and ΔS o as constants.)

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