Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined. Concept Introduction: Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows: 1. Simple cubic (SC). 2. Body centered cubic (BCC). 3. Face centered cubic (FCC).

Question

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Answer 1

Question

Chapter 3, Problem 3H.25E

(a)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined.

Concept Introduction:

Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows:

1. Simple cubic (SC).

2. Body centered cubic (BCC).

3. Face centered cubic (FCC).

(b)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

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Iodine has an orthorhombic unit cell for which the a, b, and c lattice parameters are 0.479, 0.725, and 0.978 nm, respectively. (a) If the atomic packing factor and atomic radius are 0.547 and 0.177 nm, respectively, determine the number of atoms in each unit cell. (b) The atomic weight of iodine is 126.91 g/mol; compute its theoretical density.

(a) Magnesium (Mg) has a hexagonal close-packed (HCP) crystal structure with the lattice parameter of a = 0.321 nm and c= 0.521 nm and the atomic radius is 0.173 nm. (i) What is the number of atoms per unit cell in HCP structure? (ii) Determine the atomic packing factor of the Mg unit cell. (iii) Is Mg containing an ideal atomic packing factor? You may justify your answer by evaluating the HCP c/a ratio. Subsequently, will slip be harder in Mg compared to the ideal HCP structure? Justify your answer.

A cubic unit cell contains manganese ions at the corners and fluoride ions at the center of each edge.(a) What is the empirical formula of this compound? Explain your answer.(b) What is the coordination number of the Mn3+ ion?(c) Calculate the edge length of the unit cell if the radius of a Mn3+ ion is 0.65 A.(d) Calculate the density of the compound.

Answer 2

Question

Chapter 3, Problem 3H.25E

(a)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined.

Concept Introduction:

Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows:

1. Simple cubic (SC).

2. Body centered cubic (BCC).

3. Face centered cubic (FCC).

(b)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 3, Problem 3H.25E

(a)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined.

Concept Introduction:

Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows:

1. Simple cubic (SC).

2. Body centered cubic (BCC).

3. Face centered cubic (FCC).

(b)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 4

Question

Chapter 3, Problem 3H.25E

(a)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined.

Concept Introduction:

Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows:

1. Simple cubic (SC).

2. Body centered cubic (BCC).

3. Face centered cubic (FCC).

(b)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

Expert Solution & Answer

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Answer 5

Chapter 3, Problem 3H.25E

(a)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined.

Concept Introduction:

Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows:

1. Simple cubic (SC).

2. Body centered cubic (BCC).

3. Face centered cubic (FCC).

(b)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 3, Problem 3H.25E

(a)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined.

Concept Introduction:

Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows:

1. Simple cubic (SC).

2. Body centered cubic (BCC).

3. Face centered cubic (FCC).

Answer 7

Chapter 3, Problem 3H.25E

(a)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in cesium chloride structure in solid has to be determined.

Concept Introduction:

Unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations. This can also produce whole crystals by stacking method. Basic type of unit cells is as follows:

1. Simple cubic (SC).

2. Body centered cubic (BCC).

3. Face centered cubic (FCC).

Answer 8

(b)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 3 - Prob. 3A.1AST Ch. 3 - Prob. 3A.1BST Ch. 3 - Prob. 3A.2AST Ch. 3 - Prob. 3A.2BST Ch. 3 - Prob. 3A.3AST Ch. 3 - Prob. 3A.3BST Ch. 3 - Prob. 3A.1E Ch. 3 - Prob. 3A.2E Ch. 3 - Prob. 3A.3E Ch. 3 - Prob. 3A.4E

Solution Summary: The author explains that unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations.

Concept explainers

Videos

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).

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Chapter 3 Solutions

Solution Summary: The author explains that unit cell represents lattice structure if it stacked together repeatedly with no gaps and rotations.

Concept explainers

Videos

Interpretation: Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined. Concept Introduction: Refer to part (a).

Interpretation: Coordination number of ions in rutile structure has to be determined. Concept Introduction: Refer to part (a).

Want to see the full answer?

Chapter 3 Solutions

Interpretation:

Number of cations and anions and formula units per unit cell in rutile structure in solid TiO2 has to be determined.

Concept Introduction:

Refer to part (a).

Interpretation:

Coordination number of ions in rutile structure has to be determined.

Concept Introduction:

Refer to part (a).