Concept explainers
(a)
Interpretation:
Value of factor change in pressure and root mean square speed if gas is compressed into third of its original volume has to be determined.
Concept Introduction:
Root mean square speed is square root of average value of square of molecular speeds of molecules of gas. It includes molecular weight and temperature, both of which affect kinetic energy of a gas. It is denoted by
Here,
(b)
Interpretation:
Value of factor change in pressure and root mean square speed if temperature of gas is reduced to
Concept Introduction:
Refer to part (a).
(c)
Interpretation:
Value of factor change in pressure and root mean square speed if helium gas is replaced by xenon has to be determined.
Concept Introduction:
Refer to part (a).
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Chapter 3 Solutions
CHEM PRINCIPLES LL W/ACHIEVE ONE-SEM
- 2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forwardE17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.arrow_forward
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