ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Chapter 3, Problem 3.9P
Interpretation Introduction

Interpretation: The functional groups present in oseltamivir and shikimic acids are to be identified.

Concept introduction: Functional groups are specific substituents present in the molecule that is responsible for the characteristic chemical reactions. For example, functional groups possess a carbonyl group includes aldehydes, ketones, carboxylic acids, amides, esters and acid chlorides; alcohols contain hydroxyl (OH) functional group. Amines are nitrogen containing functional groups. These are the derivatives of ammonia.

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a. Determine whether each of the Followery Molecules is in the R- On the y- Configuration 1-01"/ 1-6-4 Br 4 I el Br b. Draw The Fisher projection For all the Meso compounds that can exist FOR The Following molenle
1- Refer to the monosaccharides below to answer each of the following question(s): CH₂OH CHO CH₂OH CH₂OH 0 H- OH 0 0 HO- H H- -OH HO H HO H H OH HO- H CH₂OH H. OH HO H HO- H CH₂OH CH₂OH CH3 a. Sorbose b. Rhamnose c. Erythrulose d. Xylulose Classify each sugar by type; for example, glucose is an aldohexose. a. Xylulose is .. b. Erythrulose is . c. Sorbose is .. d. Rhamnose is .. 2- Consider the reaction below to answer the following question(s). CHO H OH CH₂OH CH₂OH HO- H HO HO + H. -OH HO OH HO. H OH OH H -OH H OH CH₂OH Q Z a. Refer to Exhibit 25-11. Place a triangle around the anomeric carbon in compound Q. Compound Z is: b. 1. the D-anomer. 2. the a-anomer. 3. the ẞ-anomer. 4. the L-anomer. c. Which anomer is the LEAST stable? d. Q and Z are cyclic examples of: a. acetals b. hemiacetals c. alditols d. hemialditols

Chapter 3 Solutions

ORGANIC CHEMISTRY

Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Which compound in each pair has the higher boiling...Ch. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.16PCh. 3 - Which compounds are water soluble? a. b. c.Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Problem 3.23 (a) What types of intermolecular...Ch. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - Prob. 3.28PCh. 3 - 3.29 Identify the functional groups in the...Ch. 3 - Prob. 3.30PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.43PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 3.45PCh. 3 - 3.46 Rank the following compounds in order of...Ch. 3 - 3.47 Which of the following molecules can hydrogen...Ch. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.49PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - 3.56 Label the electrophilic and nucleophilic...Ch. 3 - 3.57 By using only electron density arguments,...Ch. 3 - 3.58 The composition of a cell membrane is not...Ch. 3 - Prob. 3.59PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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