ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 3, Problem 3.31P
For each
hydrogen atom as
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For each alkane:
(a) classify each carbon atom as 1°, 2°, 3°, or 4°;
(b) classify each hydrogen atom as 1°, 2°, or 3°.
(a) Enter the IUPAC name for this alcohol:
CH,CH,CHCH,
ОН
Classify it as a primary, secondary, or tertiary alcohol:
(b) Enter the IUPAC name for this alcohol:
CH,CHCH,CH,CHOH
CH,
ČH,
Classify it as a primary, secondary, or tertiary alcohol:
1: Give at least five (5) uses of Alcohol and Phenol
Name
Functional Group
R-OH
Alcohols
LOH
Phenols
Based on the illustration above. What is the difference between
alcohol and phenol?
Can Phenol react with alcohol?
Chapter 3 Solutions
ORGANIC CHEMISTRY
Ch. 3 - Prob. 3.1PCh. 3 - (a) Classify the carbon atoms in each compound as...Ch. 3 - Problem 3.3 Classify a carbon atom by the number...Ch. 3 - Classify each alkyl halide and alcohol as , or...Ch. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Draw the structure of a compound of molecular...Ch. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Draw the structure of a compound fitting each...
Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Which compound in each pair has the higher boiling...Ch. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.16PCh. 3 - Which compounds are water soluble? a. b. c.Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Problem 3.23 (a) What types of intermolecular...Ch. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - Prob. 3.28PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 3.30PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.43PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 3.45PCh. 3 - 3.46 Rank the following compounds in order of...Ch. 3 - 3.47 Which of the following molecules can hydrogen...Ch. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.49PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - 3.56 Label the electrophilic and nucleophilic...Ch. 3 - 3.57 By using only electron density arguments,...Ch. 3 - 3.58 The composition of a cell membrane is not...Ch. 3 - Prob. 3.59PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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- Indicate whether each statement is true or false. (a) Alkanesdo not contain any carbon–carbon multiple bonds.(b) Cyclobutane contains a four-membered ring. (c) Alkenescontain carbon–carbon triple bonds. (d) Alkynes containcarbon–carbon double bonds. (e) Pentane is a saturatedhydrocarbon but 1-pentene is an unsaturated hydrocarbon.(f) Cyclohexane is an aromatic hydrocarbon. (g) The methylgroup contains one less hydrogen atom than methane.arrow_forwardnt Answer true or false. (a) The functional group of an alcohol is the -OH (hydroxyl) group. 1 (b) The parent name of an alcohol is the name of the longest carbon chain that contains the -OH group. (c) 1°, 2°, and 3° refer to the number of carbon groups bonded to the carbon bearing the -OH group. (d) In the IUPAC system, the presence of three -OH groups is shown by the ending -triol. (e) Glycols are diols where the two hydroxyl groups are bonded to two adjacent carbons. (f) Because of the presence of an -OH group, all alcohols are polar compounds. (g) The boiling points of alcohols decrease with increasing molecular weight. Q $ 0 % [References] L MacBook Pro Cengage Learning Cengage Technical Support Œ (arrow_forwardName these aldehydes:arrow_forward
- OH Amide H-C-0 H 100 (C) (a)arrow_forward2. Classify each compound as an alcohol, aldehyde, sugar, ketone, methyl ketone, or hydrocarbon (there should only be one of each type of compound). Hexane Ethanol Benzaldehyde Cyclohexanone Acetone (Propanone) Glucose emplearrow_forward1: Give at least five (5) uses of Etherin medicine. CH3 CH,-0-C-CH, CH, common name: methyl-t-butyl ether (MTBE) IUPAC name: 2-methoxy-2-methylpropane diphenyl ether or phenyl ether phenoxybenzene Analyze the given ether. Then describe the structural formula.arrow_forward
- Give the IUPAC name of each of the following compounds. (a) CH3CH2CH2-----OH (b) CH3---CH2---C----H || O (c) CH3CH2CH2CH2---C--CH3 || O (d) CH3---CH2----CH2----C---OH || Oarrow_forwarda) Draw the four isomers of C5H12O that can be oxidized to an aldehyde. (b) Draw the three isomers of C5H12O that can be oxidized to a ketone. (c) Draw the isomers of C5H12O that cannot be easily oxidized to an aldehyde or ketone. (d) Name any isomer that is an alcohol.arrow_forwardCyclopentane has a higher boiling point than pentane even though both compounds have the same number of carbons (49 °C vs. 36 °C). Can you suggest a reason for this phenomenon?arrow_forward
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