ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 3, Problem 3.53P
THC is the active component in marijuana, and ethanol is the alcohol in alcoholic beverages. Explain why drug screenings are able to detect the presence of THC but not ethanol weeks after substances have been introduced into the body.
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Chapter 3 Solutions
ORGANIC CHEMISTRY
Ch. 3 - Prob. 3.1PCh. 3 - (a) Classify the carbon atoms in each compound as...Ch. 3 - Problem 3.3 Classify a carbon atom by the number...Ch. 3 - Classify each alkyl halide and alcohol as , or...Ch. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Draw the structure of a compound of molecular...Ch. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Draw the structure of a compound fitting each...
Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Which compound in each pair has the higher boiling...Ch. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.16PCh. 3 - Which compounds are water soluble? a. b. c.Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Problem 3.23 (a) What types of intermolecular...Ch. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - Prob. 3.28PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 3.30PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.43PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 3.45PCh. 3 - 3.46 Rank the following compounds in order of...Ch. 3 - 3.47 Which of the following molecules can hydrogen...Ch. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.49PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - 3.56 Label the electrophilic and nucleophilic...Ch. 3 - 3.57 By using only electron density arguments,...Ch. 3 - 3.58 The composition of a cell membrane is not...Ch. 3 - Prob. 3.59PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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- The stimulant in coffee is: a. tannic acid b. theobromine c. theophylline d. caffeinearrow_forwardWhich substances can react with potassium borohydride, converting the product into alkene alcohol (assuming complete reaction)?arrow_forwardEthanol (CH3CH2OH) is the alcohol found in beverages. It is oxidized in the body to acetaldehyde by the enzyme alcohol dehydrogenase. Methanol (CH3OH), also known as wood alcohol, is converted to formaldehyde by the same enzyme. Acetaldehyde is toxic, but formaldehyde is far more toxic to humans, which is why the ingestion of relatively small amounts of methanol can cause blindness or death. One treatment for mild methanol poisoning is the administration of ethanol. Why might a doctor choose this treatment? A. Ethanol likely irreversibly binds to alcohol dehydrogenase which prevents the formation of formaldehyde. B. The doctor has given up on the patient and administers ethanol for sedation. C. Ethanol must act as a competitive inhibitor for the alcohol dehydrogenase and therefore slows the formation of formaldehyde. D. The ethanol is likely an uncompetitive inhibitor and binds to a site other than the active site of the enzyme.arrow_forward
- When diethyl ether is spilled on the skin, the skin takes on a dry appearance. Explain whether this effect is more likely due to a removal of water or a removal of natural skin oilsarrow_forwardDrinking methanol can cause blindness in humans, as well as a severe acidosis that may be life threatening. Methanol is toxic because it is converted in the liver to formaldehyde and formic acid by the enzymes alcohol dehydrogenase and aldehyde dehydrogenase. Methanol poisoning is treated with dialysis and infusions of bicarbonate and ethanol. Explain why each treatment is used.arrow_forward1. What are ketals and hemiacetals? Give their importance.arrow_forward
- Why is isopropyl alcohol (main ingredient in rubbing alcohol) used as a disinfectant?arrow_forwardWhich of the following statements about acetone is/are correct?I. Large amount of acetones are produced in the human body.II. Diabetic patients produces larger amounts of acetone.III. In severe diabetes, odor of acetone can be detected on the person's breath.IV. Acetone is partially a by-product in gasoline treatments designed for engine immiscibility to water.arrow_forwardWhat chemical test will you use to differentiate acetone from dibenzalacetone?arrow_forward
- THC is the active component in marijuana, and ethanol is the alcohol inalcoholic beverages. Explain why drug screenings are able to detect thepresence of THC but not ethanol weeks after these substances havebeen introduced into the body.arrow_forwardDefine Preparation of Alcohols ?arrow_forwardWrite the reaction, occurring in the liver, that causes theoxidation of methanol. What is the product of this reaction, and what is the possible result of the accumulation ofthe product in the body?arrow_forward
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