Poor selectivity in the formation of the brominated products when equimolar mixture of Br 2 and Cl 2 compared to the case when Br 2 alone is taken should be explained. Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism. In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation. The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

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Answer 1

Question

Chapter 3, Problem 38P

Interpretation Introduction

Interpretation: Poor selectivity in the formation of the brominated products when equimolar mixture of Br2 and Cl2 compared to the case when Br2 alone is taken should be explained.

Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.

In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation.

The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

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Answer 2

Question

Chapter 3, Problem 38P

Interpretation Introduction

Interpretation: Poor selectivity in the formation of the brominated products when equimolar mixture of Br2 and Cl2 compared to the case when Br2 alone is taken should be explained.

Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.

In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation.

The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

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Answer 3

Question

Chapter 3, Problem 38P

Interpretation Introduction

Interpretation: Poor selectivity in the formation of the brominated products when equimolar mixture of Br2 and Cl2 compared to the case when Br2 alone is taken should be explained.

Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.

In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation.

The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

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Answer 4

Question

Chapter 3, Problem 38P

Interpretation Introduction

Interpretation: Poor selectivity in the formation of the brominated products when equimolar mixture of Br2 and Cl2 compared to the case when Br2 alone is taken should be explained.

Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.

In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation.

The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

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Answer 5

Chapter 3, Problem 38P

Interpretation Introduction

Interpretation: Poor selectivity in the formation of the brominated products when equimolar mixture of Br2 and Cl2 compared to the case when Br2 alone is taken should be explained.

Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.

In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation.

The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

Answer 6

Chapter 3, Problem 38P

Interpretation Introduction

Interpretation: Poor selectivity in the formation of the brominated products when equimolar mixture of Br2 and Cl2 compared to the case when Br2 alone is taken should be explained.

Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.

In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation.

The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

Answer 7

Chapter 3, Problem 38P

Interpretation Introduction

Interpretation: Poor selectivity in the formation of the brominated products when equimolar mixture of Br2 and Cl2 compared to the case when Br2 alone is taken should be explained.

Concept introduction: The monobromination performed with ultraviolet light proceeds via radical chain mechanism.

In general, tertiary C – H bonds react in halogenations more readily than secondary those, in turn, are faster to react than primary. This can be attributed to stability of radical formed upon C – H bond cleavage via hyperconjugation.

The phenomenon of hyperconjugation refers to donation of σ electrons into the partly vacant p orbital lobes of radical carbon. More will be number of σ orbital capable of donation of electrons more is the stabilization.

Answer 8

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Answer 11

Ch. 3.1 - Prob. 3.2TIY Ch. 3.1 - Prob. 3.3E Ch. 3.4 - Prob. 3.5TIY Ch. 3.5 - Prob. 3.6E Ch. 3.7 - Prob. 3.7E Ch. 3.7 - Prob. 3.9TIY Ch. 3.9 - Prob. 3.11TIY Ch. 3.11 - Prob. 3.12E Ch. 3 - Prob. 15P Ch. 3 - Prob. 16P

Solution Summary: The author explains that the monobromination performed with ultraviolet light proceeds via radical chain mechanism. The tertiary C – H bonds react in halogenations more readily than secondary

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