
Interpretation: Potential-energy versus reaction-coordinate diagrams for the two propagation steps for monobromination of methane should be sketched.
Concept introduction: The mechanism for monobromination comprises of three stages illustrated as follows:
Step1: Initiation via homolytic cleavage of
Step2: Propagation: In first of the propagation step bromine radical from step 1 abstracts hydrogen radical from methane as follows:
In subsequent propagation step methyl radical abstracts
Step3: Termination: Radicals generated in propagation steps get quenched upon combination with one another. Thus termination steps are essentially the radical− radical combination illustrated as follows:

Want to see the full answer?
Check out a sample textbook solution
Chapter 3 Solutions
Organic Chemistry: Structure and Function
- Indicate the products obtained by mixing (3-oxo-3-phenylpropyl)triphenylphosphonium bromide with sodium hydride.arrow_forwardWe mix N-ethyl-2-hexanamine with excess methyl iodide and followed by heating with aqueous Ag2O. Indicate the major products obtained.arrow_forwardIndicate the products obtained by mixing acetophenone with iodine and NaOH.arrow_forward
- Indicate the products obtained by mixing 2-Propanone and ethyllithium and performing a subsequent acid hydrolysis.arrow_forwardIndicate the products obtained if (E)-2-butenal and 3-oxo-butanenitrile are mixed with sodium ethoxide in ethanol.arrow_forwardQuestion 3 (4 points), Draw a full arrow-pushing mechanism for the following reaction Please draw all structures clearly. Note that this intramolecular cyclization is analogous to the mechanism for halohydrin formation. COH Br + HBr Brarrow_forward
- Indicate the products obtained if 2,2-dimethylpropanal and acetaldehyde are mixed with sodium ethoxide in ethanol.arrow_forwardIndicate the products obtained if 2,2-dimethylpropanal and acetaldehyde are reacted with sodium ethoxide in ethanol.arrow_forward2,2-Dimethylpropanal and acetaldehyde are reacted with sodium ethoxide in ethanol. Indicate the products obtained.arrow_forward
- Add conditions above and below the arrow that turn the reactant below into the product below in a single transformationADS fint anditions 百 Abl res condinese NC ง Add on condtions 1.0 B H,N.arrow_forward3. Provide all the steps and reagents for this synthesis. OHarrow_forwardSteps and explanationarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
