(a) Interpretation: The bond dissociation energy of H − At with H − I is to be compared. Concept introduction: The elements in a modern periodic table are arranged in an increasing order of their atomic number . In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Answer 1

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Answer 4

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Answer 5

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 6

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 7

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

Solution Summary: The author explains that the bond dissociation energy of H- At is less than the strength of bond between two atoms in the chemical reaction.

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Chapter 3 Solutions