(a) Interpretation: The bonding and antibonding MOs of the H − Cl bond resulting from the interaction shown are to be drawn. Concept introduction: When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

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Answer 1

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Chapter 3, Problem 3.30P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs of the H−Cl bond resulting from the interaction shown are to be drawn.

Concept introduction:

When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

Interpretation Introduction

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

Please draw, not just describe!

can you draw each step on a piece of a paper please this is very confusing to me

Answer 2

Question

Chapter 3, Problem 3.30P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs of the H−Cl bond resulting from the interaction shown are to be drawn.

Concept introduction:

When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

Interpretation Introduction

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

Expert Solution & Answer

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Answer 3

Question

Chapter 3, Problem 3.30P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs of the H−Cl bond resulting from the interaction shown are to be drawn.

Concept introduction:

When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

Interpretation Introduction

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 3, Problem 3.30P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs of the H−Cl bond resulting from the interaction shown are to be drawn.

Concept introduction:

When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

Interpretation Introduction

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

Expert Solution & Answer

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See solution

Answer 5

Chapter 3, Problem 3.30P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs of the H−Cl bond resulting from the interaction shown are to be drawn.

Concept introduction:

When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

Interpretation Introduction

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

Answer 6

Chapter 3, Problem 3.30P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs of the H−Cl bond resulting from the interaction shown are to be drawn.

Concept introduction:

When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

Answer 7

Chapter 3, Problem 3.30P

Interpretation Introduction

(a)

Interpretation:

The bonding and antibonding MOs of the H−Cl bond resulting from the interaction shown are to be drawn.

Concept introduction:

When two orbitals of the same phase overlap, it results in constructive interference, i.e., a bonding MO. If the overlap is between orbitals with different phases, it results in destructive interference, i.e., an antibonding MO.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

Answer 10

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Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

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(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

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Chapter 3 Solutions

Videos

(b) Interpretation: The symmetries of the two MOs resulting from the overlap shown are to be determined. Concept introduction: When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.

Want to see the full answer?

Chapter 3 Solutions

(b)

Interpretation:

The symmetries of the two MOs resulting from the overlap shown are to be determined.

Concept introduction:

When the overlap of two orbitals is along the bond axis, the MO has σ (sigma) symmetry. If the overlap is away from the bond axis, the MO has a π symmetry.