Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 3, Problem 3.21P
Interpretation Introduction

(a)

Interpretation:

In the given molecule, the atoms that are required to be in the same plane are to be circled.

Concept introduction:

Groups that are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In the case of a double bond, the pi bond would be broken because during rotation, the overlap between the p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

Interpretation Introduction

(b)

Interpretation:

In the given molecule, the atoms that are required to be in the same plane are to be circled.

Concept introduction:

Groups that are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In the case of a double bond, the pi bond would be broken because during rotation, the overlap between the p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

Interpretation Introduction

(c)

Interpretation:

In the given molecule, the atoms that are required to be in the same plane are to be circled.

Concept introduction:

Groups that are connected by a single bond have the ability to rotate freely relative to each other. But the groups which are connected by a double bond do not rotate freely. In the case of a double bond, the pi bond would be broken because during rotation, the overlap between the p orbitals would be destroyed. When two atoms are connected by a double bond, those two atoms and all the atoms directly attached to them, prefer to lie in the same plane.

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