ELEM.PRIN.OF CHEMICAL...ABRIDGED (LL)
ELEM.PRIN.OF CHEMICAL...ABRIDGED (LL)
4th Edition
ISBN: 9781119540632
Author: FELDER
Publisher: WILEY
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Chapter 3, Problem 3.16P

Chapter 3, Problem 3.16P, 3.16. In April 2010, the worst oil spill ever recorded occurred when an explosion and tire on the

3.16. In April 2010, the worst oil spill ever recorded occurred when an explosion and tire on the Deepwater

Horizon offshore oil-drilling rig left 11 workers dead and began releasing oil into the Gulf of Mexico. One of the attempts to contain the spill involved pumping drilling mud into the well to balance the pressure of escaping oil against a column of fluid (the mud) having a density significantly higher than those of seawater and oil. In the following problems, you may assume that seawater has a specific gravity of 1.03 and that the subsea wellhead was 5053 ft below the surface of the Gulf.

  1. Estimate the gauge pressure (psig) in the Gulf at a depth of 5053 ft.
  2. Measurements indicate that the pressure inside the wellhead is 4400 psig. Suppose a pipe between the surface of the Gulf and the wellhead is filled with drilling mud and balances that pressure. Estimate the specific gravity of the drilling mud.
  3. The drilling mud is a stable slurry of seawater and barite (SG = 4.37). What is the mass fraction of barite in the slurry?
  4. What would you expect to happen if the barite weight fraction were significantly less than that estimated in Part (c)? Explain your reasoning.

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Hydrogen (H₂) is considered a clean energy carrier. For its use as a fuel, hydrogen is stored at 5 bar insidea cylindrical tank made of nickel (Ni) with 7 cm inner diameter, 1.2 mm thickness, and the length of L. Thetank is maintained at 358 K. Unfortunately, a small amount of hydrogen diffuses out of the tank, slowlydepleting its contents. You may assume that the hydrogen pressure outside the tank is essentially zero andconvective resistance inside and outside of the cylinder is negligible.• Solubility of H2 in Ni at 358 K = 0.00901 kmol/m3·bar• DH2, Ni at 358 K = 1.2 x 10-12 m2/sCalculate the maximum length of the nickel tank wall to ensure that the hydrogen loss does not exceed0.01 kg per year.
You just took out a cold soda can (at 1 oC) from the refrigerator. Calculate thetemperature of the soda can after the can is placed in a room (at 31 oC, h = 100 W/m2-K) for 60 mins (we all know that soda tastes much better when it is cold!). • k = 0.617 W/m-K, density = 996 kg/m3, Cp = 4178 J/Kg-K• Height = 10 cm & Diameter = 5 cmCalculate the temperature of the soda can surface at the middle point of the heightusing 2-D analysis.
A thick nickel wall is exposed to pure 5 bar H2(g) at 85 oC on one side of its surface (13 pts).(a) Assuming thermodynamic gas-solid equilibrium, calculate the H2 concentration at the surface ofthe nickel wall. (b) Assuming that the concentration of H2 at the surface is constant, determine the concentration ofH2 at the penetration depth in percentage of its concentration at the wall surface

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ELEM.PRIN.OF CHEMICAL...ABRIDGED (LL)

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