1. Copper is known to be toxic to fish, and in particular, the free ion Cu²+ species typically shows greatest toxicity. a. Calculate the speciation of Cu(II) for freshwater at a pH value of 8.3 as the hardness increases from 20 (soft) to 100 (moderately hard) to 200 (very hard) mg/L as CaCO3. Assume that the total divalent Cu(II) concentration is 10 µg/L. b. Based on your findings in part (a), do you think it is appropriate to set a single regulatory limit or should it depend on variables such as pH and hardness? Explain your answer.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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1. Copper is known to be toxic to fish, and in particular, the free ion Cu²+ species typically
shows greatest toxicity.
a. Calculate the speciation of Cu(II) for freshwater at a pH value of 8.3 as the hardness
increases from 20 (soft) to 100 (moderately hard) to 200 (very hard) mg/L as
CaCO3. Assume that the total divalent Cu(II) concentration is 10 µg/L.
b. Based on your findings in part (a), do you think it is appropriate to set a single
regulatory limit or should it depend on variables such as pH and hardness? Explain
your answer.
Transcribed Image Text:1. Copper is known to be toxic to fish, and in particular, the free ion Cu²+ species typically shows greatest toxicity. a. Calculate the speciation of Cu(II) for freshwater at a pH value of 8.3 as the hardness increases from 20 (soft) to 100 (moderately hard) to 200 (very hard) mg/L as CaCO3. Assume that the total divalent Cu(II) concentration is 10 µg/L. b. Based on your findings in part (a), do you think it is appropriate to set a single regulatory limit or should it depend on variables such as pH and hardness? Explain your answer.
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