1. Copper is known to be toxic to fish, and in particular, the free ion Cu²+ species typically shows greatest toxicity. a. Calculate the speciation of Cu(II) for freshwater at a pH value of 8.3 as the hardness increases from 20 (soft) to 100 (moderately hard) to 200 (very hard) mg/L as CaCO3. Assume that the total divalent Cu(II) concentration is 10 µg/L. b. Based on your findings in part (a), do you think it is appropriate to set a single regulatory limit or should it depend on variables such as pH and hardness? Explain your answer.
1. Copper is known to be toxic to fish, and in particular, the free ion Cu²+ species typically shows greatest toxicity. a. Calculate the speciation of Cu(II) for freshwater at a pH value of 8.3 as the hardness increases from 20 (soft) to 100 (moderately hard) to 200 (very hard) mg/L as CaCO3. Assume that the total divalent Cu(II) concentration is 10 µg/L. b. Based on your findings in part (a), do you think it is appropriate to set a single regulatory limit or should it depend on variables such as pH and hardness? Explain your answer.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Transcribed Image Text:1. Copper is known to be toxic to fish, and in particular, the free ion Cu²+ species typically
shows greatest toxicity.
a. Calculate the speciation of Cu(II) for freshwater at a pH value of 8.3 as the hardness
increases from 20 (soft) to 100 (moderately hard) to 200 (very hard) mg/L as
CaCO3. Assume that the total divalent Cu(II) concentration is 10 µg/L.
b. Based on your findings in part (a), do you think it is appropriate to set a single
regulatory limit or should it depend on variables such as pH and hardness? Explain
your answer.
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