Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 3, Problem 1LGP

List all the chemical species likely to be present at the end of the reaction but before adding aqueous NaHCO 3 . Note that the H 2 SO 4 was not consumed (since it is a catalyst), and is thus still available to donate a proton to atoms that can be protonated.

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. (a) Combine the following equations to construct an acid-base reaction equation, in the process drawing complete Lewis structures for both reactants and products, along with arrows to show the movement of nonbonded electrons. (b) Predict the overall direction of equilibrium in your equation and justify your answer. (c) Calculate the pK, values for the conjugate bases of the acids in your equation. NH t H20 H30® CHy Cita OH +Ho 1300 + CHzchb0s pka =15:9 + NH3 pkw =9.24
Predict whether aqueous solutions of the following substances are acidic, basic, or neutral and write hydrolysis equations for the acidic and basic solutions. (a) CsBr;  (b) Al(NO3)3;  (c) KCN;  (d) CH3NH3Cl
The preparations of two aqueous solutions are described In the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water Iitself. Write the chemical formulas of the specles that will act as acids in the 'acids' row, the formulas of the species that will act as bases In the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCH, CO, is a weak acid. do acids: 0.. 0.59 mol of KOH is added to Ar 1.0 L of a 1.3M HCH,CO, bases:| solution. other: 0.1 mol of HI is added to acids: 1.0 L of a solution that is bases:| 0.3M in both HCH,CO, and KCH, CO,. other: 0回

Chapter 3 Solutions

Organic Chemistry

Ch. 3 - Prob. 11PPCh. 3 - Prob. 12PPCh. 3 - Prob. 13PPCh. 3 - Prob. 14PPCh. 3 - Prob. 15PPCh. 3 - Prob. 16PPCh. 3 - Prob. 17PPCh. 3 - What is the conjugate base of each of the...Ch. 3 - List the bases you gave as answers to Problem 3.20...Ch. 3 - 3.22 What is the conjugate acid of each of the...Ch. 3 - List the acids you gave as answers to Problem 3.22...Ch. 3 - Designate the Lewis acid and Lewis base in each of...Ch. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Write an equation, using the curved-arrow...Ch. 3 - When methyl alcohol is treated with NaH, the...Ch. 3 - 3.30 What reaction will take place if ethyl...Ch. 3 - 3.31 (a) The of formic acid. What is the? (b)...Ch. 3 - Acid HA has pKa=20; acid HB has pKa=10. (a) Which...Ch. 3 - Prob. 30PCh. 3 - 3.34 (a) Arrange the following compounds in order...Ch. 3 - 3.35 Arrange the following compounds in order of...Ch. 3 - 3.36 Arrange the following in order of increasing...Ch. 3 - Prob. 34PCh. 3 - 3.38 Supply the curved arrows necessary for the...Ch. 3 - Glycine is an amino acid that can be obtained from...Ch. 3 - 3.40 Malonic acid, , is a diprotic acid. The for...Ch. 3 - 3.41 The free-energy change, , for the ionization...Ch. 3 - 3.42 At the enthalpy change, , for the ionization...Ch. 3 - The compound at right has (for obvious reasons)...Ch. 3 - 3.44. (a) Given the above sequence of...Ch. 3 - Prob. 42PCh. 3 - Prob. 43PCh. 3 - 3.47 As noted in Table 3.1, the of acetone, , is...Ch. 3 - Formamide (HCONH2) has a pKa of approximately 25....Ch. 3 - List all the chemical species likely to be present...Ch. 3 - Prob. 2LGPCh. 3 - Prob. 3LGPCh. 3 - Prob. 4LGPCh. 3 - Prob. 1QCh. 3 - Which of the following is the strongest base? (a)...Ch. 3 - Prob. 3QCh. 3 - Prob. 4QCh. 3 - Prob. 5QCh. 3 - Which would be the weakest base? (a) CH3CO2Na (b)...Ch. 3 - What acid-base reaction (if any) would occur when...Ch. 3 - The pKa of CH3NH3+ equals 10.6; the pKa of...Ch. 3 - 3.9 Supply the missing reagents. Ch. 3 - 3.10 Supply the missing intermediates and...
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