Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Question
Chapter 27, Problem 6P
Interpretation Introduction
Interpretation:
Number and name of each kinases involved in glycolysis should be determined.
Concept introduction:
Glycolysis is the biochemical pathway that breaks down glucose to pyruvate and produces chemical energy. The body utilizes this energy in various day to day activities. Various enzymes are involved in the glyolysis process.
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Kinases are enzymes that catalyze the addition (or removal) of a phosphate group to ( or from) a substance. ATP is also involved. How many kinases are in glycolysis? Name them.
Why are some metabolic reactions coupled to the hydrolysis of ATP?
To drive the nonspontaneous reaction
To extend the half-life of enzymes
To increase the equilibrium constant
To bypass metabolic regulation
Determine the direction that each of the reactions will progress.
Assume that the reactants and products are present in equimolar amounts. The standard free energy of hydrolysis of ATP is –30.5 kJ/mol.
fructose+ATP ____fructose 6‑phosphate+ADP
The standard free energy of hydrolysis for fructose 6‑phosphate is −15.9 kJ/mol.
3‑phosphoglycerate+ATP___1,3‑bisphosphoglycerate+ADP
The standard free energy of hydrolysis for 1,3‑bisphosphoglycerate is −49.3 kJ/mol.
creatine+ATP___creatine phosphate+ADP
The standard free energy of hydrolysis for creatine phosphate is –43.0 kJ/mol.
Chapter 27 Solutions
Introduction to General, Organic and Biochemistry
Ch. 27.1 - Prob. 27.1QCCh. 27.2 - Prob. 27.2QCCh. 27.3 - Prob. 27.3QCCh. 27.4 - Prob. 27.4QCCh. 27.5 - Prob. 27.5QCCh. 27.6 - Prob. 27.6QCCh. 27.7 - Prob. 27.7QCCh. 27.8 - Prob. 27.8QCCh. 27.9 - Prob. 27.9QCCh. 27 - Prob. 1P
Ch. 27 - What are the products of lipase-catalyzed...Ch. 27 - What is the main use of amino acids in the body?Ch. 27 - Prob. 4PCh. 27 - Prob. 5PCh. 27 - Prob. 6PCh. 27 - Prob. 7PCh. 27 - Prob. 8PCh. 27 - Prob. 9PCh. 27 - Prob. 10PCh. 27 - Prob. 11PCh. 27 - Prob. 12PCh. 27 - Prob. 13PCh. 27 - Prob. 14PCh. 27 - Prob. 15PCh. 27 - Prob. 16PCh. 27 - Prob. 17PCh. 27 - Prob. 18PCh. 27 - Prob. 19PCh. 27 - Prob. 20PCh. 27 - Two enzymes participating in ß-oxidation have the...Ch. 27 - Prob. 22PCh. 27 - Prob. 23PCh. 27 - Is the ß -oxidation of fatty acid (without the...Ch. 27 - Calculate the number of ATP molecules obtained in...Ch. 27 - Prob. 26PCh. 27 - Prob. 27PCh. 27 - Prob. 28PCh. 27 - Prob. 29PCh. 27 - Prob. 30PCh. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Prob. 33PCh. 27 - Ammonia, NH3, and ammonium ion, NH+4are both...Ch. 27 - Prob. 35PCh. 27 - Prob. 36PCh. 27 - Prob. 37PCh. 27 - Prob. 38PCh. 27 - 28-39 The metabolism of the carbon skeleton of...Ch. 27 - Prob. 40PCh. 27 - Prob. 41PCh. 27 - Prob. 42PCh. 27 - (Chemical Connections 27B ) Does gastric bypass...Ch. 27 - Prob. 44PCh. 27 - Prob. 45PCh. 27 - Prob. 46PCh. 27 - Prob. 47PCh. 27 - Prob. 48PCh. 27 - Prob. 49PCh. 27 - Prob. 50PCh. 27 - Prob. 51PCh. 27 - Prob. 52PCh. 27 - Prob. 53PCh. 27 - Write the products of the transamination reaction...Ch. 27 - Prob. 55PCh. 27 - Prob. 56PCh. 27 - Prob. 57PCh. 27 - Prob. 58PCh. 27 - Prob. 59PCh. 27 - Prob. 60PCh. 27 - Prob. 61PCh. 27 - Prob. 62PCh. 27 - Prob. 63PCh. 27 - Prob. 64PCh. 27 - Prob. 65PCh. 27 - Prob. 66PCh. 27 - Prob. 67PCh. 27 - Prob. 68PCh. 27 - Prob. 69PCh. 27 - Prob. 70PCh. 27 - Prob. 71PCh. 27 - Prob. 72PCh. 27 - Prob. 73PCh. 27 - Prob. 74PCh. 27 - Prob. 75PCh. 27 - Many soft drinks contain citric acid to add...Ch. 27 - Prob. 77PCh. 27 - Prob. 78PCh. 27 - Prob. 79PCh. 27 - Prob. 80P
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Why are so many different enzymes needed?arrow_forwardThe first step of the metabolic process known as glycolysis is the conversion of glucose to glucose- 6-phosphate. This process has a positive value for rG' Glucose + Pi Glucose-6-phosphate + H2O rG' = +13.8 kJ/mol-rxn This reaction is coupled to the hydrolysis of ATP ATP + H2O ADP + Pi rG' = -30.5 kJ/mol-rxn What is the sum of these two equations and the value of rG' for the coupled reaction? Is the coupled reaction product-favored at equilibrium?arrow_forwardWrite a generalized chemical equation, containing acronyms, for the hydrolysis of ATP to ADP.arrow_forward
- What is the general role of enzymes in the human body?arrow_forwardATP Synthase in plants has the same basic structure and function as the ATP Synthase in humans. O True O Falsearrow_forwardFor a given acid HA, it was determined that at pH 6.0 the concentration of the conjugate base [A] was 0.075 M and the acid [HA] was 0.025 M. What percent of this acid is ionized at pH 6.0? What is the pKa of this acid? What pH would this acid be 50% lonized?arrow_forward
- Chemistry What is the main aspect that the enzymes succinyl-CoA synthetase, pyruvate kinase, and phosphoglycerate kinase have in common?arrow_forwardGive an account of the total ATP yield when I molecule of glucose is converted to carbon dioxide and water?arrow_forwardUse the following information corresponding to 1 Molar concentrations of reactants and products for Questions 7 -13. ΔHo’ = -63.39 kJ/mol and ΔS o’ = -0.1255 kJ/molK. Glycerol + ATP → ADP + 3-Phosphoglycerate: ΔHo’ = -63.39 kJ/mol and ΔS o’ = -0.1255 kJ/molK. At what temperature (if any) is this reaction excergonic? Report your answer in Kelvin using inequality signs with out and extra spaces added in. For example T=100.00K T>100.00K T<100.00K T</=100.00K less than or equal to T>/=100.00K greater than or equal toarrow_forward
- What are the three kinds of enzymes-controlled reaction so that the chemical bond energy from a certain nutrietiens is released to the cell in a form of ATP?arrow_forwardATP is produced during synthesis of compounds. O True O Falsearrow_forwardWhy is the conversion of lactic acid from the blood into glucose in the liver in an organism’s best interest?arrow_forward
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