Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 27, Problem 27.53P
Interpretation Introduction
Interpretation:
Explain the activation of phosphorylase enzyme.
Concept Introduction:
Phosphorylase is an enzyme which synthesis starch.
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Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
The reverse of this reaction is always
spontaneous but proceeds faster at
temperatures above -48. °C.
ΔΗ is
(pick one)
✓
AS is
(pick one)
B
This reaction is spontaneous except below
114. °C but proceeds at a slower rate
below 135. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
C
This reaction is exothermic and proceeds
faster at temperatures above -43. °C.
(pick one)
AS is
(pick one) v
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A student proposes the following Lewis structure for the perchlorate (CIO) io
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Assign a formal charge to each atom in the student's Lewis structure.
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Chapter 27 Solutions
Introduction to General, Organic and Biochemistry
Ch. 27 - Prob. 27.1PCh. 27 - Prob. 27.2PCh. 27 - (a) How many membranes do mitochondria have? (b)...Ch. 27 - Prob. 27.4PCh. 27 - Prob. 27.5PCh. 27 - Prob. 27.6PCh. 27 - Prob. 27.7PCh. 27 - Prob. 27.8PCh. 27 - Prob. 27.9PCh. 27 - Prob. 27.10P
Ch. 27 - What kind of chemical bond exists between the...Ch. 27 - Prob. 27.12PCh. 27 - Which atoms in the flavin portion of FAD are...Ch. 27 - NAD+ has two ribose units in its structure; FAD...Ch. 27 - Prob. 27.15PCh. 27 - The ribitol in FAD is bound to phosphate. What is...Ch. 27 - What kind Of chemical bond exists between the...Ch. 27 - Prob. 27.18PCh. 27 - Prob. 27.19PCh. 27 - Prob. 27.20PCh. 27 - Prob. 27.21PCh. 27 - Prob. 27.22PCh. 27 - Prob. 27.23PCh. 27 - Prob. 27.24PCh. 27 - Prob. 27.25PCh. 27 - Prob. 27.26PCh. 27 - Prob. 27.27PCh. 27 - Prob. 27.28PCh. 27 - Prob. 27.29PCh. 27 - Prob. 27.30PCh. 27 - Prob. 27.31PCh. 27 - Prob. 27.32PCh. 27 - Prob. 27.33PCh. 27 - Prob. 27.34PCh. 27 - Prob. 27.35PCh. 27 - Prob. 27.36PCh. 27 - Prob. 27.37PCh. 27 - Prob. 27.38PCh. 27 - Prob. 27.39PCh. 27 - Prob. 27.40PCh. 27 - Prob. 27.41PCh. 27 - Prob. 27.42PCh. 27 - Prob. 27.43PCh. 27 - Prob. 27.44PCh. 27 - Prob. 27.45PCh. 27 - Prob. 27.46PCh. 27 - Prob. 27.47PCh. 27 - Prob. 27.48PCh. 27 - Prob. 27.49PCh. 27 - A hexose (C6) enters the common metabolic pathway...Ch. 27 - Prob. 27.51PCh. 27 - Prob. 27.52PCh. 27 - Prob. 27.53PCh. 27 - Prob. 27.54PCh. 27 - (Chemical Connections 27A) Oligomycin is an anti-...Ch. 27 - Prob. 27.56PCh. 27 - Prob. 27.57PCh. 27 - Prob. 27.58PCh. 27 - Prob. 27.59PCh. 27 - Prob. 27.60PCh. 27 - Prob. 27.61PCh. 27 - What is the basic difference in the functional...Ch. 27 - Prob. 27.63PCh. 27 - Prob. 27.64PCh. 27 - Prob. 27.65PCh. 27 - Prob. 27.66PCh. 27 - Prob. 27.67PCh. 27 - Prob. 27.68PCh. 27 - Prob. 27.69PCh. 27 - Prob. 27.70PCh. 27 - Prob. 27.71PCh. 27 - Prob. 27.72PCh. 27 - Prob. 27.73PCh. 27 - Prob. 27.74PCh. 27 - Prob. 27.75PCh. 27 - Prob. 27.76PCh. 27 - Prob. 27.77PCh. 27 - Prob. 27.78PCh. 27 - Some soft drinks contain citric acid as flavoring....Ch. 27 - Prob. 27.80PCh. 27 - Prob. 27.81PCh. 27 - Prob. 27.82PCh. 27 - Prob. 27.83PCh. 27 - Prob. 27.84PCh. 27 - Prob. 27.85PCh. 27 - Prob. 27.86PCh. 27 - Prob. 27.87PCh. 27 - Prob. 27.88PCh. 27 - Prob. 27.89PCh. 27 - Why is it somewhat misleading to study biochemi-...Ch. 27 - Prob. 27.91PCh. 27 - Prob. 27.92PCh. 27 - Prob. 27.93PCh. 27 - Prob. 27.94PCh. 27 - Prob. 27.95PCh. 27 - Prob. 27.96PCh. 27 - Prob. 27.97PCh. 27 - Prob. 27.98PCh. 27 - Prob. 27.99PCh. 27 - Prob. 27.100PCh. 27 - Prob. 27.101PCh. 27 - Prob. 27.102PCh. 27 - Prob. 27.103PCh. 27 - Prob. 27.104P
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- Decide whether these proposed Lewis structures are reasonable. proposed Lewis structure Yes. Is the proposed Lewis structure reasonable? Cl- : 2: :Z: :Z: N—N : 0: C C1: O CO No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* ☐ Yes. No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | Yes. No, it has the wrong number of valence electrons. The correct number is: No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0". ☑arrow_forwardUse the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions ΔΗ is (pick one) A This reaction is faster above 103. °C than below. AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous only above -9. °C. AS is (pick one) ΔΗ is (pick one) C The reverse of this reaction is always spontaneous. AS is (pick one) 18 Ararrow_forwardUse the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A The reverse of this reaction is always spontaneous but proceeds slower at temperatures below 41. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous except above 94. °C. AS is (pick one) This reaction is always spontaneous, but ΔΗ is (pick one) C proceeds slower at temperatures below −14. °C. AS is (pick one) Х 00. 18 Ar 무ㅎ B 1 1arrow_forward
- Draw the product of the reaction shown below. Ignore inorganic byproducts. + H CH3CH2OH HCI Drawingarrow_forwardplease explain this in simple termsarrow_forwardK Most Reactive Na (3 pts) Can the metal activity series (shown on the right) or a standard reduction potential table explain why potassium metal can be prepared from the reaction of molten KCI and Na metal but sodium metal is not prepared from the reaction of molten NaCl and K metal? Show how (not). Ca Mg Al с Zn Fe Sn Pb H Cu Ag Au Least Reactivearrow_forward
- (2 pts) Why is O2 more stable as a diatomic molecule than S2?arrow_forwardDraw the Lewis structure for the polyatomic phosphite (PO¾³¯) a anion. Be sure to include all resonance structures that satisfy the octet rule. C I A [ ]¯arrow_forwardDecide whether these proposed Lewis structures are reasonable. proposed Lewis structure Is the proposed Lewis structure reasonable? Yes. :0: Cl C C1: 0=0: : 0 : : 0 : H C N No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* ☐ Yes. No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* Yes. ☐ No, it has the wrong number of valence electrons. The correct number is: ☐ No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* | * If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0".arrow_forward
- Draw the Lewis structure for the polyatomic trisulfide anion. Be sure to include all resonance structures that satisfy the octet rule. с [ ] - Garrow_forward1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…arrow_forwardPlease draw, not just describe!arrow_forward
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