Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 27, Problem 27.29P
Interpretation Introduction
Interpretation:
The validation of the fact that ATP is directly produced during any step in the citric acid cycle is to be stated with an explanation.
Concept introduction:
Citric acid cycle is also known as the Krebs cycle. It is a series of chemical processes in the aerobic organisms that involve the oxidation of acetyl-CoA obtained as a product from glycolysis. It involves a total of eight steps.
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
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160
120
80
40
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200
160
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DEPT 135
T
200
160
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Draw the unknown amide.
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Dow
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Chapter 27 Solutions
Introduction to General, Organic and Biochemistry
Ch. 27 - Prob. 27.1PCh. 27 - Prob. 27.2PCh. 27 - (a) How many membranes do mitochondria have? (b)...Ch. 27 - Prob. 27.4PCh. 27 - Prob. 27.5PCh. 27 - Prob. 27.6PCh. 27 - Prob. 27.7PCh. 27 - Prob. 27.8PCh. 27 - Prob. 27.9PCh. 27 - Prob. 27.10P
Ch. 27 - What kind of chemical bond exists between the...Ch. 27 - Prob. 27.12PCh. 27 - Which atoms in the flavin portion of FAD are...Ch. 27 - NAD+ has two ribose units in its structure; FAD...Ch. 27 - Prob. 27.15PCh. 27 - The ribitol in FAD is bound to phosphate. What is...Ch. 27 - What kind Of chemical bond exists between the...Ch. 27 - Prob. 27.18PCh. 27 - Prob. 27.19PCh. 27 - Prob. 27.20PCh. 27 - Prob. 27.21PCh. 27 - Prob. 27.22PCh. 27 - Prob. 27.23PCh. 27 - Prob. 27.24PCh. 27 - Prob. 27.25PCh. 27 - Prob. 27.26PCh. 27 - Prob. 27.27PCh. 27 - Prob. 27.28PCh. 27 - Prob. 27.29PCh. 27 - Prob. 27.30PCh. 27 - Prob. 27.31PCh. 27 - Prob. 27.32PCh. 27 - Prob. 27.33PCh. 27 - Prob. 27.34PCh. 27 - Prob. 27.35PCh. 27 - Prob. 27.36PCh. 27 - Prob. 27.37PCh. 27 - Prob. 27.38PCh. 27 - Prob. 27.39PCh. 27 - Prob. 27.40PCh. 27 - Prob. 27.41PCh. 27 - Prob. 27.42PCh. 27 - Prob. 27.43PCh. 27 - Prob. 27.44PCh. 27 - Prob. 27.45PCh. 27 - Prob. 27.46PCh. 27 - Prob. 27.47PCh. 27 - Prob. 27.48PCh. 27 - Prob. 27.49PCh. 27 - A hexose (C6) enters the common metabolic pathway...Ch. 27 - Prob. 27.51PCh. 27 - Prob. 27.52PCh. 27 - Prob. 27.53PCh. 27 - Prob. 27.54PCh. 27 - (Chemical Connections 27A) Oligomycin is an anti-...Ch. 27 - Prob. 27.56PCh. 27 - Prob. 27.57PCh. 27 - Prob. 27.58PCh. 27 - Prob. 27.59PCh. 27 - Prob. 27.60PCh. 27 - Prob. 27.61PCh. 27 - What is the basic difference in the functional...Ch. 27 - Prob. 27.63PCh. 27 - Prob. 27.64PCh. 27 - Prob. 27.65PCh. 27 - Prob. 27.66PCh. 27 - Prob. 27.67PCh. 27 - Prob. 27.68PCh. 27 - Prob. 27.69PCh. 27 - Prob. 27.70PCh. 27 - Prob. 27.71PCh. 27 - Prob. 27.72PCh. 27 - Prob. 27.73PCh. 27 - Prob. 27.74PCh. 27 - Prob. 27.75PCh. 27 - Prob. 27.76PCh. 27 - Prob. 27.77PCh. 27 - Prob. 27.78PCh. 27 - Some soft drinks contain citric acid as flavoring....Ch. 27 - Prob. 27.80PCh. 27 - Prob. 27.81PCh. 27 - Prob. 27.82PCh. 27 - Prob. 27.83PCh. 27 - Prob. 27.84PCh. 27 - Prob. 27.85PCh. 27 - Prob. 27.86PCh. 27 - Prob. 27.87PCh. 27 - Prob. 27.88PCh. 27 - Prob. 27.89PCh. 27 - Why is it somewhat misleading to study biochemi-...Ch. 27 - Prob. 27.91PCh. 27 - Prob. 27.92PCh. 27 - Prob. 27.93PCh. 27 - Prob. 27.94PCh. 27 - Prob. 27.95PCh. 27 - Prob. 27.96PCh. 27 - Prob. 27.97PCh. 27 - Prob. 27.98PCh. 27 - Prob. 27.99PCh. 27 - Prob. 27.100PCh. 27 - Prob. 27.101PCh. 27 - Prob. 27.102PCh. 27 - Prob. 27.103PCh. 27 - Prob. 27.104P
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