General, Organic, and Biological Chemistry Seventh Edition
7th Edition
ISBN: 9781305767867
Author: H. Stephan Stoker
Publisher: Cengage Learning
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Chapter 26, Problem 26.92EP
Interpretation Introduction
Interpretation: To determine the fate of the iron
Concept introduction: In the body, red blood cells deliver oxygen and remove carbon dioxide from the body tissues. Mature red blood cells have hemoglobin which is responsible for the oxygen carrying ability of the red blood cells.
Hemoglobin is a heme protein present in the red blood cells. The protein part is called globin and the non-protein part is heme. Heme is the prosthetic group that contains 4 pyrrole groups bonded together and has an iron atom in the center. The structure of the heme group is:
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
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Potential Energy (kJ)
600
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0
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-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 26 Solutions
General, Organic, and Biological Chemistry Seventh Edition
Ch. 26.1 - Which of the following statements about dietary...Ch. 26.1 - Dietary protein materials as they leave the...Ch. 26.1 - The inactive form of pepsin is converted to its...Ch. 26.1 - Which of the following is not a proteolytic...Ch. 26.2 - The dominant use for the amino acids of the amino...Ch. 26.2 - The most abundant amino acid in the amino acid...Ch. 26.2 - Prob. 3QQCh. 26.3 - Prob. 1QQCh. 26.3 - Prob. 2QQCh. 26.3 - The net effect of transamination is to collect the...
Ch. 26.3 - Prob. 4QQCh. 26.3 - Prob. 5QQCh. 26.3 - Most aminotransferases are specific for the keto...Ch. 26.4 - Which of the following statements concerning the...Ch. 26.4 - Prob. 2QQCh. 26.4 - The two fuels for the urea cycle are a. carbamoyl...Ch. 26.4 - Prob. 4QQCh. 26.4 - Prob. 5QQCh. 26.4 - Prob. 6QQCh. 26.5 - Which of the following statements concerning the...Ch. 26.5 - Prob. 2QQCh. 26.5 - Prob. 3QQCh. 26.5 - Prob. 4QQCh. 26.6 - Prob. 1QQCh. 26.6 - How many of the standard amino acids are...Ch. 26.6 - The simplest pathways for amino acid biosynthesis...Ch. 26.7 - Prob. 1QQCh. 26.7 - Which of the following statements concerning the...Ch. 26.7 - Prob. 3QQCh. 26.7 - In the degradation of heme, the iron atom present...Ch. 26.8 - In degradation of the sulfur-containing amino acid...Ch. 26.8 - Prob. 2QQCh. 26.8 - Prob. 3QQCh. 26.8 - Prob. 4QQCh. 26.9 - Prob. 1QQCh. 26.9 - Prob. 2QQCh. 26.9 - Prob. 3QQCh. 26.10 - Prob. 1QQCh. 26.10 - Prob. 2QQCh. 26.10 - Prob. 3QQCh. 26 - Prob. 26.1EPCh. 26 - Indicate whether each of the following aspects of...Ch. 26 - Indicate whether each of the following pairings of...Ch. 26 - Indicate whether each of the following pairings of...Ch. 26 - Indicate whether each of the following statements...Ch. 26 - Prob. 26.6EPCh. 26 - Prob. 26.7EPCh. 26 - Prob. 26.8EPCh. 26 - Prob. 26.9EPCh. 26 - Prob. 26.10EPCh. 26 - Prob. 26.11EPCh. 26 - Prob. 26.12EPCh. 26 - Prob. 26.13EPCh. 26 - Prob. 26.14EPCh. 26 - Indicate whether each of the following situations...Ch. 26 - Indicate whether each of the following situations...Ch. 26 - Prob. 26.17EPCh. 26 - Prob. 26.18EPCh. 26 - Prob. 26.19EPCh. 26 - Prob. 26.20EPCh. 26 - Prob. 26.21EPCh. 26 - Prob. 26.22EPCh. 26 - Prob. 26.23EPCh. 26 - Prob. 26.24EPCh. 26 - Prob. 26.25EPCh. 26 - Prob. 26.26EPCh. 26 - Prob. 26.27EPCh. 26 - Prob. 26.28EPCh. 26 - Prob. 26.29EPCh. 26 - Prob. 26.30EPCh. 26 - Prob. 26.31EPCh. 26 - Prob. 26.32EPCh. 26 - Prob. 26.33EPCh. 26 - Prob. 26.34EPCh. 26 - Prob. 26.35EPCh. 26 - Prob. 26.36EPCh. 26 - Prob. 26.37EPCh. 26 - Prob. 26.38EPCh. 26 - Prob. 26.39EPCh. 26 - Prob. 26.40EPCh. 26 - Prob. 26.41EPCh. 26 - Prob. 26.42EPCh. 26 - Prob. 26.43EPCh. 26 - Draw the structure of the -keto acid produced from...Ch. 26 - Prob. 26.45EPCh. 26 - Prob. 26.46EPCh. 26 - Prob. 26.47EPCh. 26 - Prob. 26.48EPCh. 26 - Prob. 26.49EPCh. 26 - Prob. 26.50EPCh. 26 - Prob. 26.51EPCh. 26 - Prob. 26.52EPCh. 26 - Prob. 26.53EPCh. 26 - Prob. 26.54EPCh. 26 - Prob. 26.55EPCh. 26 - Prob. 26.56EPCh. 26 - Prob. 26.57EPCh. 26 - Prob. 26.58EPCh. 26 - Prob. 26.59EPCh. 26 - Prob. 26.60EPCh. 26 - Prob. 26.61EPCh. 26 - Prob. 26.62EPCh. 26 - Prob. 26.63EPCh. 26 - Prob. 26.64EPCh. 26 - Prob. 26.65EPCh. 26 - Prob. 26.66EPCh. 26 - Prob. 26.67EPCh. 26 - Prob. 26.68EPCh. 26 - Prob. 26.69EPCh. 26 - Prob. 26.70EPCh. 26 - Prob. 26.71EPCh. 26 - Prob. 26.72EPCh. 26 - Prob. 26.73EPCh. 26 - Prob. 26.74EPCh. 26 - Prob. 26.75EPCh. 26 - Prob. 26.76EPCh. 26 - Prob. 26.77EPCh. 26 - Prob. 26.78EPCh. 26 - Prob. 26.79EPCh. 26 - Prob. 26.80EPCh. 26 - Prob. 26.81EPCh. 26 - Prob. 26.82EPCh. 26 - Prob. 26.83EPCh. 26 - Prob. 26.84EPCh. 26 - Prob. 26.85EPCh. 26 - Prob. 26.86EPCh. 26 - Prob. 26.87EPCh. 26 - Prob. 26.88EPCh. 26 - Prob. 26.89EPCh. 26 - Prob. 26.90EPCh. 26 - Prob. 26.91EPCh. 26 - Prob. 26.92EPCh. 26 - Prob. 26.93EPCh. 26 - Prob. 26.94EPCh. 26 - Prob. 26.95EPCh. 26 - Prob. 26.96EPCh. 26 - Prob. 26.97EPCh. 26 - Which bile pigment is responsible for the...Ch. 26 - Prob. 26.99EPCh. 26 - Prob. 26.100EPCh. 26 - Prob. 26.101EPCh. 26 - Prob. 26.102EPCh. 26 - Prob. 26.103EPCh. 26 - Prob. 26.104EPCh. 26 - Prob. 26.105EPCh. 26 - Prob. 26.106EPCh. 26 - Prob. 26.107EPCh. 26 - Prob. 26.108EPCh. 26 - Prob. 26.109EPCh. 26 - Prob. 26.110EPCh. 26 - Prob. 26.111EPCh. 26 - Prob. 26.112EPCh. 26 - Prob. 26.113EPCh. 26 - Prob. 26.114EPCh. 26 - Prob. 26.115EPCh. 26 - Prob. 26.116EP
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