a) Interpretation: How to prepare the compound shown is to be given. Concept introduction: The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base. To give: How to prepare the compound shown.

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Answer 1

Question

Chapter 23.SE, Problem 70AP

Interpretation Introduction

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

Interpretation Introduction

b)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The Michael addition reaction between the enamine produced by reacting cyclohexanone with pyrrolidine with vinylnitrile and hydrolyzing the product yield the product required.

To give:

How to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

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Answer 2

Question

Chapter 23.SE, Problem 70AP

Interpretation Introduction

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

Interpretation Introduction

b)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The Michael addition reaction between the enamine produced by reacting cyclohexanone with pyrrolidine with vinylnitrile and hydrolyzing the product yield the product required.

To give:

How to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

Expert Solution & Answer

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Answer 3

Question

Chapter 23.SE, Problem 70AP

Interpretation Introduction

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

Interpretation Introduction

b)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The Michael addition reaction between the enamine produced by reacting cyclohexanone with pyrrolidine with vinylnitrile and hydrolyzing the product yield the product required.

To give:

How to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

Expert Solution & Answer

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Answer 4

Question

Chapter 23.SE, Problem 70AP

Interpretation Introduction

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

Interpretation Introduction

b)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The Michael addition reaction between the enamine produced by reacting cyclohexanone with pyrrolidine with vinylnitrile and hydrolyzing the product yield the product required.

To give:

How to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

Expert Solution & Answer

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Answer 5

Chapter 23.SE, Problem 70AP

Interpretation Introduction

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

Interpretation Introduction

b)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The Michael addition reaction between the enamine produced by reacting cyclohexanone with pyrrolidine with vinylnitrile and hydrolyzing the product yield the product required.

To give:

How to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

Answer 6

Chapter 23.SE, Problem 70AP

Interpretation Introduction

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

Answer 7

Chapter 23.SE, Problem 70AP

Interpretation Introduction

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

Answer 8

Interpretation Introduction

b)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The Michael addition reaction between the enamine produced by reacting cyclohexanone with pyrrolidine with vinylnitrile and hydrolyzing the product yield the product required.

To give:

How to prepare the compound shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The Michael addition reaction between the enamine produced by reacting cyclohexanone with pyrrolidine with vinylnitrile and hydrolyzing the product yield the product required.

To give:

How to prepare the compound shown.

Answer 10

Interpretation Introduction

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

Answer 11

Interpretation Introduction

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

Answer 12

Interpretation Introduction

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

Answer 13

Interpretation Introduction

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

Answer 14

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Answer 15

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Answer 19

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Answer 20

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Answer 21

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Answer 25

Ch. 23.1 - Prob. 1P Ch. 23.1 - Prob. 2P Ch. 23.3 - Prob. 3P Ch. 23.3 - Prob. 4P Ch. 23.4 - Prob. 5P Ch. 23.4 - 1-Butanol is prepared commercially by a route that...Ch. 23.4 - Prob. 7P Ch. 23.5 - Prob. 8P Ch. 23.6 - Prob. 9P Ch. 23.6 - What product would you Expect to obtain from base...

a) Interpretation: How to prepare the compound shown is to be given. Concept introduction: The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base. To give: How to prepare the compound shown.

Concept explainers

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.

Chapter 23 Solutions

a) Interpretation: How to prepare the compound shown is to be given. Concept introduction: The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base. To give: How to prepare the compound shown.

Concept explainers

a) Interpretation: How to prepare the compound shown is to be given. Concept introduction: The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base. To give: How to prepare the compound shown.

c) Interpretation: How to prepare the compound shown is to be given. Concept introduction: The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide. To give: How to prepare the compound shown.

d) Interpretation: How to prepare the compound shown is to be given. Concept introduction: The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification. To give: How to prepare the compound shown.

Chapter 23 Solutions

a)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two successive aldol condensation reaction of cyclohexanone with two molecules of benzaldehyde innthe presence of a base.

To give:

How to prepare the compound shown.

c)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction takes place in two steps i) Abstraction of a proton by a base ii) Nucleophilic attack of the carbanion on allyl bromide.

To give:

How to prepare the compound shown.

d)

Interpretation:

How to prepare the compound shown is to be given.

Concept introduction:

The reaction involves two steps i) Abstraction of α-hydrogen atom by the base ii) Attack of the enolate on diethyl oxalate followed by acidification.

To give:

How to prepare the compound shown.