Concept explainers
a)
Interpretation:
How to prepare the cyclohexanone shown by combining a Stork enamine reaction with an intramolecular aldol condensation is to be shown.
Concept introduction:
The steps involved in the reaction are i) Reaction of the cyclic
To give:
How to prepare the cyclohexanone shown by combining a Stork enamine reaction with an intramolecular aldol condensation.
b)
Interpretation:
How to prepare the cyclohexanone shown by combining a Stork enamine reaction with an intramolecular aldol condensation is to be shown.
Concept introduction:
The steps involved in the reaction are i) Reaction of the cyclic ketone with pyrrolidine ii) Michael addition of enamine to cyclohexanone iii) A proton transfer iv) Hydrolysis of the enamine to eliminate the amine v) Abstraction of a proton from the diketone vi) Internal aldol reaction to form the second ring vii) Protonation and dehydration.
To give:
How to prepare the cyclohexanone shown by combining a Stork enamine reaction with an intramolecular aldol condensation.
c)
Interpretation:
How to prepare the cyclohexanone shown by combining a Stork enamine reaction with an intramolecular aldol condensation is to be shown.
Concept introduction:
The steps involved in the reaction are i) Reaction of the cyclic ketone with pyrrolidine ii) Michael addition of enamine to cyclohexanone iii) A proton transfer iv) Hydrolysis of the enamine to eliminate the amine v) Abstraction of a proton from the diketone vi) Internal aldol reaction to form the second ring vii) Protonation and dehydration.
To give:
How to prepare the cyclohexanone shown by combining a Stork enamine reaction with an intramolecular aldol condensation.
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Chapter 23 Solutions
Organic Chemistry
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EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT