Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 23, Problem 24P

(a)

Interpretation Introduction

Interpretation:

The coenzyme transfers an acyl group from one substrate to another should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

Thiamine pyrophosphate (TPP) is the coenzyme required by enzymes that catalyse the transfer of an acyl group.

(b)

Interpretation Introduction

Interpretation:

The function of FAD on the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(c)

Interpretation Introduction

Interpretation:

The function of NAD+ in the pyruvate dehydrogenase complex should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(d)

Interpretation Introduction

Interpretation:

The reaction necessary for proper blood clotting is catalysed by vitamin KH2 should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(e)

Interpretation Introduction

Interpretation:

The coenzyme are used for decarboxylation reaction should be determined.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(f)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(g)

Interpretation Introduction

Interpretation:

The coenzyme should be determined for carboxylation reaction.

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

(h)

Interpretation Introduction

Interpretation:

The various kinds of substrates should be determined for the decarboxylation coenzyme work on

Concept introduction:

Cofactors that are organic molecule are called coenzymes;

Coenzymes are derived from Vitamins which are substance needed in small amounts for normal body function that the body cannot synthesize in adequate amounts.

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30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in class, but the partition function that describes the translational and rotational motion of a homonuclear diatomic molecule is given by Itrans (V,T) = = 2πmkBT h² V grot (T) 4π²IKBT h² Where h is Planck's constant and I is molecular moment of inertia. The overall partition function is qmolec Qtrans qrot. Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a volume of 1 m³. Here is some useful data: Moment of inertia: I2 I 7.46 x 10- 45 kg m² 2 O2 I 1.91 x 101 -46 kg m²
K for each reaction step. Be sure to account for all bond-breaking and bond-making steps. HI HaC Drawing Arrows! H3C OCH3 H 4 59°F Mostly sunny H CH3 HO O CH3 'C' CH3 Select to Add Arrows CH3 1 L H&C. OCH3 H H H H Select to Add Arrows Q Search Problem 30 of 20 H. H3C + :0: H CH3 CH3 20 H2C Undo Reset Done DELL
Draw the principal organic product of the following reaction.

Chapter 23 Solutions

Organic Chemistry (8th Edition)

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