
Concept explainers
(a)
Interpretation: The theoretical yield of
Concept introduction:
Number of moles of a substance,
From its given mass is,
Theoretical yield is the maximum product yield that can be expected based on the masses of the reactants and the reaction stoichiometry.
2-Iodobenzoic acid is a crystaline solid and it can be prepared from 2-aminobenzoic acid treated with
The reaction can be represnted as follows,
(a)

Answer to Problem 104IL
Theoretical yield of benzoic acid is
Explanation of Solution
From the given data,
Let’s calculate the number of moles of 2-amino benzoic acid:
From the given:
Let’s calculate the number of moles of
From the given:
Let’s calculate the number of moles of
From the equation , we can see that 1 mole of 2- amino benzoic acid gives 1 mole of 1-iodo benzoic acid .
For this conversion required 1 mole of
Theoretically produced
Molar mass of 2-iodobenzoic acid =
Therefore, theoretical yield of 2-iodobenzoic acid is
(b)
Interpretation: To Check the possibilty of isomers for 2-iodobenzoic acid
Concept introduction:
2-Iodobenzoic acid is a crystaline solid and it can be prepared from 2-aminobenzoic acid treated with
The reaction can be represnted as follows,
Two compounds that have the same molecular formula, but have different structural formulas are called isomers.
(b)

Answer to Problem 104IL
No other possible isomers for 2-Iodobenzoic acid.
Explanation of Solution
No other isomers of 2-iodo benzoic acid are possible in this reaction because the
(c)
Interpretation: The molar mass of the product formed in the given reaction has to be determined. And check whether the calculated molar mass is in reasonable agreement with the theoretical molar mass or not.
Concept introduction:
2-Iodobenzoic acid is a crystaline solid and it can be prepared from 2-aminobenzoic acid treated with
The reaction can be represnted as follows,
Concentration of solutions can be expressed in various terms; molarity is one such concentration expressing term.
Molarity (M) of a solution is the number of gram moles of a solute present in one liter of the solution.
A solution containing one gram mole or
Amount of substance (mol) can be determined by using the equation,
The molar mass of an element or compound is the mass in grams of 1 mole of that substance, and it is expressed in the unit of grams per mol (g/mol).
Theoretical yield is the maximum product yield that can be expected based on the masses of the reactants and the reaction stoichiometry.
(c)

Answer to Problem 104IL
Molar mass of 2-Iodobenzoic acid
There is only
Explanation of Solution
From the given,
Let’s calculate the number of mole of
Let’s calculate molar mass of 2-iodo benzoic acid.
Theoretical mass 2-Iodobenzoic acid is
Therefore, there is only
We can say that it is in reasonable agreement with theoretical molar mass.
Want to see more full solutions like this?
Chapter 23 Solutions
Bundle: Chemistry & Chemical Reactivity, Loose-Leaf Version, 9th + OWLv2, 4 terms (24 Months) Printed Access Card
- Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward(a) Sketch the 'H NMR of the following chemical including the approximate chemical shifts, the multiplicity (splitting) of all signals and the integration (b) How many signals would you expect in the 13C NMR? CH3arrow_forwardDraw the Show the major and minor product(s) for the following reaction mechanisms for both reactions and show all resonance structures for any Explain why the major product is favoured? intermediates H-Brarrow_forward
- 3. Draw ALL THE POSSBILE PRODUCTS AND THE MECHANISMS WITH ALL RESONANCE STRUCTURES. Explain using the resonance structures why the major product(s) are formed over the minor product(s). H₂SO4, HONO CHarrow_forward7. Provide the product(s), starting material(s) and/or condition(s) required for the No mechanisms required. below reaction HO + H-I CI FO Br2, FeBr3 O I-Oarrow_forward6. Design the most efficient synthesis of the following product starting from phenot Provide the reaction conditions for each step (more than one step is required) and explain the selectivity of each reaction. NO MECHANISMS ARE REQUIRED. OH step(s) CIarrow_forward
- What is the skeletal structure of the product of the following organic reaction?arrow_forwardIf a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forwardWhat is the major organic product of the following nucleophilic acyl substitution reaction of an acid chloride below?arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningMacroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks ColeOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning



