For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned. Concept Introduction : If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively. There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given. The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes . If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent. If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results. If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer. To find : Categorize the number of alkyl groups attached to nitrogen atom

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Answer 1

Question

Chapter 22.2, Problem 1PTS

(a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

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Answer 2

Question

Chapter 22.2, Problem 1PTS

(a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22.2, Problem 1PTS

(a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

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Answer 4

Question

Chapter 22.2, Problem 1PTS

(a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 22.2, Problem 1PTS

(a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 6

Chapter 22.2, Problem 1PTS

(a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 7

Chapter 22.2, Problem 1PTS

(a)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 8

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 9

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 10

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 11

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 12

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 13

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 14

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 15

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 16

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 17

(f)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, general or IUPAC names have to be assigned.

Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc. carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc. carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configuration results.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

To find: Categorize the number of alkyl groups attached to nitrogen atom

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 22.2 - Prob. 1LTS Ch. 22.2 - Prob. 1PTS Ch. 22.2 - Prob. 2PTS Ch. 22.2 - Prob. 3ATS Ch. 22.3 - Prob. 4CC Ch. 22.3 - Prob. 5CC Ch. 22.3 - Prob. 6CC Ch. 22.3 - Prob. 7CC Ch. 22.3 - Prob. 8CC Ch. 22.3 - Prob. 9CC

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Chapter 22 Solutions