The name for the given by-product has to be assigned. Concept Introduction: Guidelines to assign names for amines : Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified. Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine. Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent. Step 4: The parent chain is numbered starting from the side that is closer to the amine group. Step 5: Then the locants, name and configuration have to be assigned.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.2, Problem 3ATS

(a)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(b)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(c)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.2, Problem 3ATS

(a)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(b)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(c)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.2, Problem 3ATS

(a)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(b)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(c)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 22.2, Problem 3ATS

(a)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(b)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(c)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

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Answer 5

Chapter 22.2, Problem 3ATS

(a)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(b)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

(c)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

Answer 6

Chapter 22.2, Problem 3ATS

(a)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

Answer 7

Chapter 22.2, Problem 3ATS

(a)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

Answer 8

(b)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

Answer 9

(b)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

Answer 10

(c)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

Answer 11

(c)

Interpretation Introduction

Interpretation: The name for the given by-product has to be assigned.

Concept Introduction:

Guidelines to assign names for amines:

Step 1: The alkyl groups that are connected to the nitrogen atom have to be identified.

Step 2: Determine whether the compound should be named as alkyl amine or as an alkanamine. If the alkyl groups are simple, then the corresponding amine is named as alkylamine whereas if the alkyl groups are complex, then the corresponding amine is named as alkanamine.

Step 3: If the compound is named as alkanamine then the more complex group has to be chosen as the parent.

Step 4: The parent chain is numbered starting from the side that is closer to the amine group.

Step 5: Then the locants, name and configuration have to be assigned.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 22.2 - Prob. 1LTS Ch. 22.2 - Prob. 1PTS Ch. 22.2 - Prob. 2PTS Ch. 22.2 - Prob. 3ATS Ch. 22.3 - Prob. 4CC Ch. 22.3 - Prob. 5CC Ch. 22.3 - Prob. 6CC Ch. 22.3 - Prob. 7CC Ch. 22.3 - Prob. 8CC Ch. 22.3 - Prob. 9CC

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