The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base. Concept introduction: Acidity of alpha protons of β -dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

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Answer 1

Question

Chapter 22.15, Problem 22.46P

(a)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(b)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(c)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(d)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

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Answer 2

Question

Chapter 22.15, Problem 22.46P

(a)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(b)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(c)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(d)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

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Answer 3

Question

Chapter 22.15, Problem 22.46P

(a)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(b)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(c)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(d)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

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Answer 4

Question

Chapter 22.15, Problem 22.46P

(a)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(b)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(c)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(d)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

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Answer 5

Chapter 22.15, Problem 22.46P

(a)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(b)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(c)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

(d)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 6

Chapter 22.15, Problem 22.46P

(a)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 7

Chapter 22.15, Problem 22.46P

(a)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The resonance forms are to be drawn for the enolate ions formed during the treatment of given compound with a strong base.

Concept introduction:

Acidity of alpha protons of β-dicarbonyl compounds is higher than the hydroxy protons of water and alcohols. This is due to the presence of two carbonyl groups beta to each other. Its enolate ion is also more stable.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.2A - Prob. 22.2P Ch. 22.4 - Without looking back, propose a mechanism for the...Ch. 22.4 - Prob. 22.8P Ch. 22.4 - Prob. 22.9P Ch. 22.5A - Prob. 22.10P Ch. 22.5A - Prob. 22.11P Ch. 22.5B - Prob. 22.12P Ch. 22.5B - Predict the products of the following reactions....Ch. 22.5B - Which compounds will give positive iodoform tests?...Ch. 22.5C - Propose a mechanism for the acid-catalyzed...

Solution Summary: The author explains that the resonance forms are drawn for the enolate ions formed during the treatment of given compound with a strong base.

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Chapter 22 Solutions