EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Chapter 22.13, Problem 24P
Draw the mechanism for the hydroxide ion-catalyzed cleavage of fructose-l.6-bisphosphate.
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In one electrode: Pt, H2(1 atm) | H+(a=1), the interchange current density at 298K is 0.79 mA·cm-2. If the voltage difference of the interface is +5 mV. What will be the correct intensity at pH = 2?. Maximum transfer voltage and beta = 0.5.
In a Pt electrode, H2(1 atm) | H+(a=1), the interchange current density of an electrode is 0.79 mA cm-2. ¿Qué corriente flow across the electrode of área 5 cm2 when the difference in potential of the interface is +5 mV?.
If the current voltage is n = 0.14 V, indicate which of the 2 voltage
formulas of the ley of Tafel must be applied
i
a
a) == exp (1-B).
xp[(1 - ß³):
Fn
Fn
a
b) == exp B
RT
RT
Chapter 22 Solutions
EBK ORGANIC CHEMISTRY
Ch. 22.2 - Compare each of the mechanisms listed here with...Ch. 22.2 - Prob. 3PCh. 22.2 - Prob. 4PCh. 22.3 - a. Draw the mechanism for the following reaction...Ch. 22.5 - Prob. 7PCh. 22.5 - Propose a mechanism for the Co2+ catalyzed...Ch. 22.6 - Prob. 9PCh. 22.7 - Prob. 10PCh. 22.7 - Prob. 12PCh. 22.7 - Prob. 13P
Ch. 22.9 - Which of the following amino acid side chains can...Ch. 22.9 - Which of the following C-terminal peptide bonds is...Ch. 22.9 - Carboxypeptidase A has esterase activity as well...Ch. 22.10 - Arginine and lysine side chains fit into trypsins...Ch. 22.10 - Explain why serine proteases do not catalyze...Ch. 22.11 - If H2 18O is used in the hydrolysis reaction...Ch. 22.11 - Draw the pH-activity profile for an enzyme that...Ch. 22.12 - The pHactivity profile for glucose-6-phosphate...Ch. 22.12 - Prob. 23PCh. 22.13 - Draw the mechanism for the hydroxide ion-catalyzed...Ch. 22.13 - What advantage does the enzyme gain by forming an...Ch. 22.13 - Prob. 26PCh. 22.13 - Prob. 27PCh. 22.13 - Aldolase shows no activity if it is incubated with...Ch. 22 - Which of the following parameters would be...Ch. 22 - Prob. 29PCh. 22 - Prob. 30PCh. 22 - Prob. 31PCh. 22 - Indicate the type of catalysis that is occurring...Ch. 22 - The deuterium kinetic isotope effect (KH2O/KD2O)...Ch. 22 - Prob. 34PCh. 22 - Co2+ catalyzes the hydrolysis of the lactam shown...Ch. 22 - there are two kinds of aldolases. Class I...Ch. 22 - Prob. 37PCh. 22 - The hydrolysis of the ester shown here is...Ch. 22 - Prob. 39PCh. 22 - At pH = 12, the rate of hydrolysis of ester A is...Ch. 22 - 2-Acetoxycyclohexyl tosylate reacts with acetate...Ch. 22 - Proof that an imine was formed between aldolase...Ch. 22 - Prob. 43PCh. 22 - a. Explain why the alkyl halide shown here reacts...Ch. 22 - Triosephosphate isomerase (TIM) catalyzes the...
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- If the current voltage is n = 0.14 V. Indicate which of the 2 formulas must be applied a) = a T = i exp[(1 - p) F Fn Fn b) i==exp B RTarrow_forwardTopic: Photochemistry and Photophysics of Supramoleculesarrow_forwardTwo cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 Carrow_forward
- With the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.arrow_forwardApply the NANSTE law to the MnO4- + 8H+ + 5e- ⇄ Mn2+ + 4H2Oarrow_forwardIn the Nernst Law, how much is RT / F?arrow_forward
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