Concept explainers
(a)
Interpretation:
The synthesis of
Concept introduction:
In
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The reaction of
Figure 1
The synthesis of
(b)
Interpretation:
The synthesis of
Concept introduction:
In organic chemistry, the class of functional group which is derived from conjugated diene by replacing one double bond with a carbonyl group. The dienone compound is in conjugation to each other.
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The reaction of
Figure 2
The synthesis of
(c)
Interpretation:
The synthesis of
Concept introduction:
An ester is a derivative of carboxylic which is obtained by replacing the
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
Diethyl heptanedioate in presence of
Figure 3
The synthesis of
(d)
Interpretation:
The synthesis of
Concept introduction:
An ester is a derivative of carboxylic which is obtained by replacing the
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The reaction of diethyl malonate in presence of base and then
Figure 4
The synthesis of
(e)
Interpretation:
The synthesis of
Concept introduction:
An ester is a derivative of
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The reaction of ethyl acrylate with ammonia forms amide derivative. It undergoes reduction reaction with
Figure 5
The synthesis of
(f)
Interpretation:
The synthesis of
Concept introduction:
In organic chemistry, the compound with the molecular formula
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The reaction of acrylonitrile with
Figure 6
The synthesis of
(g)
Interpretation:
The synthesis of
Concept introduction:
Carboxylic acid is a class of organic compound contains a
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
Esterification of phenylacetic acid forms ethyl
Figure 7
The synthesis of
(h)
Interpretation:
The synthesis of
Concept introduction:
In Aldol condensation reaction, the base abstracts an acidic proton from the
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The reaction of acetophenone in presence of base abstracts a
Figure 8
The synthesis of
(i)
Interpretation:
The synthesis of deuterium substituted diphenylethanol from phenylacetic acid is to be stated.
Concept introduction:
Carboxylic acid is a class of organic compound that contains a
Answer to Problem 22.82AP
The synthesis of di-deuterium substituted diphenyl ethanol from phenylacetic acid is shown below.
Explanation of Solution
Reaction of
Figure 9
The synthesis of deuterium substituted diphenyl ethanol from phenylacetic acid is shown in Figure 9.
(j)
Interpretation:
The synthesis of tetra-deuterium substituted product from cyclohexanone is to be stated.
Concept introduction:
In organic chemistry, the carbonyl compound is a class of functional group which contains a
Answer to Problem 22.82AP
The synthesis of tetra-deuterium substituted product from cyclohexanone is shown below.
Explanation of Solution
The reaction of cyclohexanone with
Figure 10
The synthesis of tetra-deuterium substituted from cyclohexanone is shown in Figure 10.
(k)
Interpretation:
The synthesis of
Concept introduction:
Friedel Craft acylation is an electrophilic aromatic substitution reaction. In this reaction, the synthesis of the monoacylated product takes place from the reaction between aromatic rings and acyl chlorides. The organic reaction in which an organohalide is reacted with alcohols or phenols to form ethers is Willamson synthesis reaction.
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The reaction of phenol with methyl halide forms methylphenyl ether. It reacts with acetyl chloride followed by chlorination in sunlight. Then it reacts with phenol to give the desired product. The synthesis of
Figure 11
The synthesis of
(l)
Interpretation:
The synthesis of
Concept introduction:
An ester is a derivative of carboxylic which is obtained by replacing the
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
Methylation of diethyl malonate in the presence of sodium ethoxide and
Figure 12
The synthesis of
(m)
Interpretation:
The synthesis of
Concept introduction:
An ester is a derivative of carboxylic which is obtained by replacing the
Answer to Problem 22.82AP
The synthesis of
Explanation of Solution
The hydrolysis reaction of
Figure13
The synthesis of
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Chapter 22 Solutions
EBK ORGANIC CHEMISTRY
- 2. Please consider the two all 'cis' isomers of trimethylcyclohexane drawn below. Draw the two chair conformers of each stereoisomer below (1 and 2) and calculate their torsional interaction energies in order to identify the lower energy conformer for each stereoisomer. Based on your calculations, state which of the two stereoisomers 1 and 2 is less stable and which is more stable. [1,3-diaxial CH3 CH3 = 3.7kcal/mol; 1,3-diaxial CH3 H = 0.88kcal/mol; cis-1,2 (axial:equatorial) CH3 CH3 = 0.88kcal/mol; trans-1,2-diequatorial CH3 CH3 = 0.88kcal/mol) all-cis-1,2,3- 1 all-cis-1,2,4- 2arrow_forwardNonearrow_forwardWhat is the mechanism by which the 1,4 product is created? Please draw it by hand with arrows and stuff.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning