(a) Interpretation: The curved arrow mechanism for the given reaction is to be predicted. Concept introduction: Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K 2 CO 3 acts as a strong base.

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Answer 1

Question

Chapter 22, Problem 22.87AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K2CO3 acts as a strong base.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. KOH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

The addition of proton in the chemical reaction is known as protonation. The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 22, Problem 22.87AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K2CO3 acts as a strong base.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. KOH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

The addition of proton in the chemical reaction is known as protonation. The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

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Answer 3

Question

Chapter 22, Problem 22.87AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K2CO3 acts as a strong base.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. KOH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

The addition of proton in the chemical reaction is known as protonation. The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Expert Solution & Answer

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Answer 4

Question

Chapter 22, Problem 22.87AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K2CO3 acts as a strong base.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. KOH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

The addition of proton in the chemical reaction is known as protonation. The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

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See solution

Answer 5

Chapter 22, Problem 22.87AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K2CO3 acts as a strong base.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. KOH acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

The addition of proton in the chemical reaction is known as protonation. The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents.

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Answer 6

Chapter 22, Problem 22.87AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K2CO3 acts as a strong base.

Answer 7

Chapter 22, Problem 22.87AP

Interpretation Introduction

(a)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also known as proton acceptors. Base accepts a proton and forms conjugate acid. The compound K2CO3 acts as a strong base.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaH acts as a strong base to form carbanion in the chemical reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaH acts as a strong base to form carbanion in the chemical reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. KOH acts as a strong base to form carbanion in the chemical reaction.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. KOH acts as a strong base to form carbanion in the chemical reaction.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

The addition of proton in the chemical reaction is known as protonation. The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

The addition of proton in the chemical reaction is known as protonation. The substances which on addition removes oxygen atom or hydrogen atom from the other substance, that is, reduces the other substances are known as reducing agents.

Answer 18

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Answer 19

Interpretation Introduction

(g)

Interpretation:

The curved arrow mechanism for the given reaction is to be predicted.

Concept introduction:

Bronsted-Lowry base are those species which accept a proton. They are also called proton acceptor. Base accepted a proton and forms conjugate acid. NaOEt acts as a strong base to form carbanion in the chemical reaction.

Answer 20

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Answer 21

Expert Solution & Answer

Answer 22

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Answer 23

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains the curved arrow mechanism for the given reaction. Bronsted-Lowry base accepts a proton and forms conjugate acid.

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Chapter 22 Solutions