Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 22, Problem 22.61P
Interpretation Introduction

Interpretation:

The synthesis route for a given transformation using benzene and any alcohol is to be predicted.

Concept introduction:

Primary alcohol on reaction with KMnO4,KOH form carboxylic acid which on further reaction with thionyl chloride (SOCl2) form acid chloride. A reaction of acid chloride with 2 equiv. of Grignard reagent followed by proton transfer form a tertiary alcohol.

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PLEASE READ!!! I DONT WANT EXAMPLES, I DONT WANT WORDS OR PARAGRAPHS FOR THE MECHANISM!!! THANKS First image: QUESTION 6. I have to show, with ARROWS and STRUCTURES, the mechanism of the reaction at the bottom. Also I have to show by mecanism why the reaction wouldn't work if the alcohol was primary. I also tried to draw the mechanism, tell me what to change. Please note that its an AMIDE thats formed not an AMINE the nitrogen has ONE hydrogen and one Phenyl-C-Phenyl. I already asked for this mechanism and got as a final product ...-NH2 not whats shown on the picture, thank you Ths second part. QUESTION 3. I just need a way to synthesize the lactone A, I already started please continue from where I left it  Second image: I simply need the products, substrates or reagents, thank you
Indicate how to prepare a 10% sodium hydroxide (NaOH) solution to a slightly alkaline pH.

Chapter 22 Solutions

Organic Chemistry: Principles and Mechanisms (Second Edition)

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