EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
Question
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Chapter 22, Problem 22.14P

(a)

Interpretation Introduction

Interpretation:

The predominant form of carboxylic acid and an amine at pH 3.0 have to be drawn.

Concept Introduction:

If pKa is greater than the pH value then protonation occurs at that pH.

(b)

Interpretation Introduction

Interpretation:

The component that will be expected to be eluted first has to be identified and explained.

Concept Introduction:

In chromatography elution order depends on the solubility of the compound in stationary phase. Polar compounds are generally insoluble in non-polar stationary phase and hence eluted first. Whereas non-polar compounds are insoluble in polar stationary phase hence eluted first.

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