The structural differences between α-and β-glucose and their polymers are to be stated. Concept introduction: Carbohydrates are polyhydroxy aldehyde and ketones , with an empirical formula C n ( H 2 O ) n . Glucose is a monosaccharide (or simple sugar) having a molecular formula of C 6 H 12 O 6 . The D-glucose exists in two forms i.e. alpha and beta glucose and these two cyclic forms are the building blocks of two different polymers. So when molecules of each joined chemically, a polymer of starch and cellulose are formed. To determine: The structural differences between α-and β-glucose and the polymers formed by each.
The structural differences between α-and β-glucose and their polymers are to be stated. Concept introduction: Carbohydrates are polyhydroxy aldehyde and ketones , with an empirical formula C n ( H 2 O ) n . Glucose is a monosaccharide (or simple sugar) having a molecular formula of C 6 H 12 O 6 . The D-glucose exists in two forms i.e. alpha and beta glucose and these two cyclic forms are the building blocks of two different polymers. So when molecules of each joined chemically, a polymer of starch and cellulose are formed. To determine: The structural differences between α-and β-glucose and the polymers formed by each.
Solution Summary: The author explains that the structural differences between -and -glucose and their polymers are to be rightly stated.
Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.
Chapter 22, Problem 107E
Interpretation Introduction
Interpretation: The structural differences between α-and β-glucose and their polymers are to be stated.
Concept introduction: Carbohydrates are polyhydroxy aldehyde and ketones, with an empirical formula Cn(H2O)n. Glucose is a monosaccharide (or simple sugar) having a molecular formula of C6H12O6. The D-glucose exists in two forms i.e. alpha and beta glucose and these two cyclic forms are the building blocks of two different polymers. So when molecules of each joined chemically, a polymer of starch and cellulose are formed.
To determine: The structural differences between α-and β-glucose and the polymers formed by each.
There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 22 Solutions
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