Bundle: Chemistry, 10th + Laboratory Handbook for General Chemistry, 3rd + Student Resource Center Printed Access Card + Student Solutions Manual for ... Access Card for Zumdahl/Zumdahl/DeCoste
10th Edition
ISBN: 9781337816465
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 22, Problem 40E
Interpretation Introduction
Interpretation: The structural isomers in Exercise 37 that exhibit cis-trans isomerism are to be stated.
Concept introduction: Structural isomerism occurs when two compounds have the same number of atoms, but the spatial arrangement of the atoms is different from each other. These isomers have the same formula, but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond, but in trans isomer, they are on the opposite side of the double bond.
To determine: The structural isomers in Exercise 37 that exhibit cis-trans isomerism.
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
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14375.11
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17997.10
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10.0
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12988.01
80.0
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57530.75
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A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
Chapter 22 Solutions
Bundle: Chemistry, 10th + Laboratory Handbook for General Chemistry, 3rd + Student Resource Center Printed Access Card + Student Solutions Manual for ... Access Card for Zumdahl/Zumdahl/DeCoste
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Ch. 22 - Prob. 11RQCh. 22 - Describe the structural differences between DNA...Ch. 22 - Prob. 1QCh. 22 - Prob. 2QCh. 22 - Prob. 3QCh. 22 - Prob. 4QCh. 22 - Prob. 5QCh. 22 - Prob. 6QCh. 22 - Prob. 7QCh. 22 - Give an example reaction that would yield the...Ch. 22 - Prob. 9QCh. 22 - Prob. 10QCh. 22 - Prob. 11QCh. 22 - Prob. 12QCh. 22 - Is the primary, secondary, or tertiary structure...Ch. 22 - Prob. 14QCh. 22 - Prob. 15ECh. 22 - Prob. 16ECh. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Draw the structural formula for each of the...Ch. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Name each of the following cyclic alkanes, and...Ch. 22 - Prob. 25ECh. 22 - Draw the structures for two examples of...Ch. 22 - Name each of the following alkenes. a. CH2 = CH ...Ch. 22 - Name each of the following alkenes or alkynes. a....Ch. 22 - Prob. 29ECh. 22 - Give the structure for each of the following. a....Ch. 22 - Prob. 31ECh. 22 - Cumene is the starting material for the industrial...Ch. 22 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 22 - Prob. 34ECh. 22 - There is only one compound that is named...Ch. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Draw all the structural isomers of C5H10. 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