The test for the presence of glucose with an aldehyde group is given to be found only in the open chain form but not in the cyclic form. This phenomenon is to be explained. Concept introduction: Carbohydrates are naturally occurring organic compounds. As the name implies carbohydrates are hydrates of carbon and have general formula of C X ( H 2 O ) Y . Basically, carbohydrates are polyhydroxy aldehyde and ketones , for examples, glucose and fructose. Glucose is a reducing sugar as it has an aldehyde group and its presence is detected by Tollen’s, Benedicts or Fehlings test. To determine: An explanation corresponding to the fact that the test for the presence of glucose with an aldehyde group is found only in the open chain form but not in the cyclic form.
The test for the presence of glucose with an aldehyde group is given to be found only in the open chain form but not in the cyclic form. This phenomenon is to be explained. Concept introduction: Carbohydrates are naturally occurring organic compounds. As the name implies carbohydrates are hydrates of carbon and have general formula of C X ( H 2 O ) Y . Basically, carbohydrates are polyhydroxy aldehyde and ketones , for examples, glucose and fructose. Glucose is a reducing sugar as it has an aldehyde group and its presence is detected by Tollen’s, Benedicts or Fehlings test. To determine: An explanation corresponding to the fact that the test for the presence of glucose with an aldehyde group is found only in the open chain form but not in the cyclic form.
Solution Summary: The author explains that the test for the presence of glucose with an aldehyde group is found only in the open chain form.
Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.
Chapter 22, Problem 106E
Interpretation Introduction
Interpretation: The test for the presence of glucose with an aldehyde group is given to be found only in the open chain form but not in the cyclic form. This phenomenon is to be explained.
Concept introduction: Carbohydrates are naturally occurring organic compounds. As the name implies carbohydrates are hydrates of carbon and have general formula of
CX(H2O)Y. Basically, carbohydrates are
polyhydroxy aldehyde and ketones, for examples, glucose and fructose. Glucose is a reducing sugar as it has an aldehyde group and its presence is detected by Tollen’s, Benedicts or Fehlings test.
To determine: An explanation corresponding to the fact that the test for the presence of glucose with an aldehyde group is found only in the open chain form but not in the cyclic form.
2. A graph shown below shows first ionization energies for elements from H to Ne.
First ionization energy/kJ mol
2500
2000
1500
1000
500
T
T
T
T
1
2
3
5
6
7
8
9
10
Atomic number
a) Using arguments of electronic structure, explain why ionization energy of Li is much
lower than that of H.
(2 points)
then dips at O.
b) Using the same arguments, explain why ionization energy increases from B to N, and
(3 points)
Give the name of this compound, including stereochemistry if relevant:
CICH2
CH3
Br
CH₂CH=CH2
Write in the product, including stereochemistry where relevant, for these
reactions. See end of ch. 8, p. 301-303.
1. 03
a) 2-methyl-2-pentene
->
2. Zn, H*
Br2
b) 1-ethylcyclopentene
-->
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